498270

1-Chloro-N,N,2-trimethyl-1-propenylamine

96%

Manufacturer: Sigma Aldrich

CAS Number: 26189-59-3

Synonym(S): Ghosez′s reagent

Select a Size

Pack Size SKU Availability Price
5 ML 498270-5-ML In Stock ₹ 18,478.28
50 ML 498270-50-ML In Stock ₹ 1,12,027.93
250 ML 498270-250-ML In Stock ₹ 4,71,396.28

498270 - 5 ML

₹ 18,478.28

In Stock

Quantity

1

Base Price: ₹ 18,478.28

GST (18%): ₹ 3,326.09

Total Price: ₹ 21,804.37

Quality Level

100

Assay

96%

refractive index

n20/D 1.453 (lit.)

bp

129-130 °C (lit.)

density

1.01 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CN(C)\C(Cl)=C(\C)C

InChI

1S/C6H12ClN/c1-5(2)6(7)8(3)4/h1-4H3

InChI key

GQIRIWDEZSKOCN-UHFFFAOYSA-N

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Description

  • Application: 1-Chloro-N,N,2-trimethyl-1-propenylamine is an acid halogenation reagent developed by Ghosez, that enables the conversion of carboxylic acids into the corresponding chlorides under strictly neutral conditions.[1] This method was successfully used in the total synthesis of caloporoside[2], roseophilin[3], (-)-enniatin B[4], (±)-epimeloscine and (±)-meloscine.[5]

SAFETY INFORMATION

Pictograms

GHS02,GHS05

Signal Word

Danger

Hazard Statements

H226,H314

Precautionary Statements

P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Sigma Aldrich

498270

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Quality Level:
100

Assay:
96%

refractive index:
n20/D 1.453 (lit.)

bp:
129-130 °C (lit.)

density:
1.01 g/mL at 25 °C (lit.)

storage temp.:
2-8°C

SMILES string:
CN(C)\C(Cl)=C(\C)C

InChI:
1S/C6H12ClN/c1-5(2)6(7)8(3)4/h1-4H3

InChI key:
GQIRIWDEZSKOCN-UHFFFAOYSA-N

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100

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refractive index:
__

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__

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2-8°C

SMILES string:
Nc1cccc(c1)C#C

InChI:
1S/C8H7N/c1-2-7-4-3-5-8(9)6-7/h1,3-6H,9H2

InChI key:
NNKQLUVBPJEUOR-UHFFFAOYSA-N

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SMILES string:
Cl.Cl.Nc1cc(N)c(O)cc1O

InChI:
1S/C6H8N2O2.2ClH/c7-3-1-4(8)6(10)2-5(3)9;;/h1-2,9-10H,7-8H2;2*1H

InChI key:
KUMOYHHELWKOCB-UHFFFAOYSA-N

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density:
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__

InChI:
__

InChI key:
__