713589

p-Toluenesulfonyl azide solution

11-15 % (w/w) in toluene, 97%

Manufacturer: Sigma Aldrich

CAS Number: 941-55-9

Synonym(S): 4-Methylbenzenesulfonyl azide solution, p-Toluenesulfonazide solution, Tosyl azide solution

Select a Size

Pack Size SKU Availability Price
25 G 713589-25-G In Stock ₹ 15,100.88
100 G 713589-100-G In Stock ₹ 31,511.58

713589 - 25 G

₹ 15,100.88

In Stock

Quantity

1

Base Price: ₹ 15,100.88

GST (18%): ₹ 2,718.158

Total Price: ₹ 17,819.038

Quality Level

100

Assay

≥96.5% (HPLC)97%

form

liquid

concentration

11-15 % (w/w) in toluene

refractive index

n20/D 1.502

density

~0.90 g/mL at 20 °C

storage temp.

2-8°C

SMILES string

Cc1ccc(cc1)S(=O)(=O)N=[N+]=[N-]

InChI

1S/C7H7N3O2S/c1-6-2-4-7(5-3-6)13(11,12)10-9-8/h2-5H,1H3

InChI key

NDLIRBZKZSDGSO-UHFFFAOYSA-N

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Description

  • General description: p-Toluenesulfonyl azide is used as a nitrene source and in the synthesis of N-sulfimines, N-tosylphosphinimines, and N-sulfoximines.[1]
  • Application: p-Toluenesulfonyl azide solution can be employed as a reagent along with alkyne, and amine in the three-component coupling reaction for the synthesis of N-sulfonylamidines in presence of copper catalyst.[2]It can also be used in the synthesis of N-sulfonyl-1,2,3-triazoles by azide-alkyne cycloaddition reaction in the presence of copper catalyst.[3]

SAFETY INFORMATION

Pictograms

GHS02,GHS06,GHS08

Signal Word

Danger

Hazard Statements

H225,H300,H304,H315,H336,H361d,H373,H412

Precautionary Statements

P201 - P210 - P273 - P301 + P310 - P303 + P361 + P353 - P331

Hazard Classifications

Acute Tox. 2 Oral - Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

Target Organs

Central nervous system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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713589

11-15 % (w/w) in toluene, 97%...


Quality Level:
100

Assay:
≥96.5% (HPLC)97%

form:
liquid

concentration:
11-15 % (w/w) in toluene

refractive index:
n20/D 1.502

density:
~0.90 g/mL at 20 °C

storage temp.:
2-8°C

SMILES string:
Cc1ccc(cc1)S(=O)(=O)N=[N+]=[N-]

InChI:
1S/C7H7N3O2S/c1-6-2-4-7(5-3-6)13(11,12)10-9-8/h2-5H,1H3

InChI key:
NDLIRBZKZSDGSO-UHFFFAOYSA-N

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__

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SMILES string:
O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]C([O-])=O

InChI:
1S/CH2O3.2Na.10H2O/c2-1(3)4;;;;;;;;;;;;/h(H2,2,3,4);;;10*1H2/q;2*+1;;;;;;;;;;/p-2

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SMILES string:
O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]C([O-])=O

InChI:
1S/CH2O3.2Na.10H2O/c2-1(3)4;;;;;;;;;;;;/h(H2,2,3,4);;;10*1H2/q;2*+1;;;;;;;;;;/p-2

InChI key:
__

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SMILES string:
O=C(O[Na])O[Na]

InChI:
1S/CH2O3.2Na/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key:
CDBYLPFSWZWCQE-UHFFFAOYSA-L