D178454

Dimethyl phosphite

98%

Manufacturer: Sigma Aldrich

CAS Number: 868-85-9

Synonym(S): Dimethoxyphosphine oxide, Dimethyl hydrogen phosphite, Dimethyl hydrogen phosphonate, Dimethyl phosphonate, Hydrogen dimethyl phosphite

Select a Size

Pack Size SKU Availability Price
25 G D178454-25-G In Stock ₹ 2,316.55
500 G D178454-500-G In Stock ₹ 3,777.93

D178454 - 25 G

₹ 2,316.55

In Stock

Quantity

1

Base Price: ₹ 2,316.55

GST (18%): ₹ 416.979

Total Price: ₹ 2,733.529

Quality Level

200

Assay

98%

form

liquid

impurities

≤0.5% trimethyl phosphate≤1% methyl alcohol

refractive index

n20/D 1.402 (lit.)

bp

170-171 °C (lit.)

density

1.2 g/mL at 25 °C (lit.)

SMILES string

[H]P(=O)(OC)OC

InChI

1S/C2H7O3P/c1-4-6(3)5-2/h6H,1-2H3

InChI key

HZCDANOFLILNSA-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-179-6658
Sigma Aldrich Fine Chemicals Biosciences Dimethyl Phosphite | 868-85-9 | MFCD00044633 | 25g
Sigma Aldrich Fine Chemicals Biosciences ₹ 5,980.64
AB72973
868-85-9 | Dimethyl phosphite
A2B Chem --

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Description

  • Application: Dimethyl phosphite is used in the synthesis of α-aminophosphonates, which are medicinally important phosphorus analogs of amino acids, by treating with an amine and an aldehyde or a ketone.[1][2] It can also be employed in asymmetric hydrophosphonylation of aldehydes to synthesize optically active α-hydroxy phosphonates.[3]

SAFETY INFORMATION

Pictograms

GHS08,GHS07

Signal Word

Warning

Hazard Statements

H317,H341,H351,H412

Precautionary Statements

P202 - P261 - P273 - P280 - P302 + P352 - P308 + P313

Hazard Classifications

Aquatic Chronic 3 - Carc. 2 - Muta. 2 - Skin Sens. 1

WGK

WGK 1

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Show Difference

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Sigma Aldrich

D178454

98%...


Quality Level:
200

Assay:
98%

form:
liquid

impurities:
≤0.5% trimethyl phosphate≤1% methyl alcohol

refractive index:
n20/D 1.402 (lit.)

bp:
170-171 °C (lit.)

density:
1.2 g/mL at 25 °C (lit.)

SMILES string:
[H]P(=O)(OC)OC

InChI:
1S/C2H7O3P/c1-4-6(3)5-2/h6H,1-2H3

InChI key:
HZCDANOFLILNSA-UHFFFAOYSA-N

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__

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__

SMILES string:
CC/C=C\C/C=C\C/C=C\C/C=C\C/C=C\CCCCCC(O)=O

InChI:
1S/C22H34O2/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19-20-21-22(23)24/h3-4,6-7,9-10,12-13,15-16H,2,5,8,11,14,17-21H2,1H3,(H,23,24)/b4-3-,7-6-,10-9-,13-12-,16-15-

InChI key:
__

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Sigma Aldrich

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European Pharmacopoeia (EP) Referen...


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form:
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impurities:
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SMILES string:
[H][C@@]1(C[C@H](O)[C@H](O[C@@]2([H])C[C@H](O)[C@H](O[C@@]3([H])C[C@H](O)[C@H](O)[C@@H](C)O3)[C@@H](C)O2)[C@@H](C)O1)O[C@H]4CC[C@@]5(C)[C@]([H])(CC[C@]6([H])[C@]5([H])CC[C@]7(C)[C@]([H])(CC[C@]67O)C8=CC(=O)OC8)C4

InChI:
1S/C41H64O13/c1-20-36(46)29(42)16-34(49-20)53-38-22(3)51-35(18-31(38)44)54-37-21(2)50-33(17-30(37)43)52-25-8-11-39(4)24(15-25)6-7-28-27(39)9-12-40(5)26(10-13-41(28,40)47)23-14-32(45)48-19-23/h14,20-22,24-31,33-38,42-44,46-47H,6-13,15-19H2,1-5H3/t20-,21-,22-,24-,25+,26-,27+,28-,29+,30+,31+,33+,34+,35+,36-,37-,38-,39+,40-,41+/m1/s1

InChI key:
WDJUZGPOPHTGOT-XUDUSOBPSA-N

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__

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__