227994

Bis(dibenzylideneacetone)palladium(0)

Manufacturer: Sigma Aldrich

CAS Number: 32005-36-0

Synonym(S): Palladium(0) bis(dibenzylideneacetone), Pd(dba)2

Select a Size

Pack Size SKU Availability Price
500 MG 227994-500-MG In Stock ₹ 4,500.00
2 G 227994-2-G In Stock ₹ 14,163.60
5 G 227994-5-G In Stock ₹ 19,130.00
50 G 227994-50-G In Stock ₹ 1,91,907.90

227994 - 500 MG

₹ 4,500.00

In Stock

Quantity

1

Base Price: ₹ 4,500.00

GST (18%): ₹ 810.00

Total Price: ₹ 5,310.00

form

powder

Quality Level

100

reaction suitability

core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

SMILES string

[Pd].O=C(/C=C/c1ccccc1)\C=C\c2ccccc2.O=C(/C=C/c3ccccc3)\C=C\c4ccccc4

InChI

1S/2C17H14O.Pd/c2*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;/h2*1-14H;/b2*13-11+,14-12+;

InChI key

UKSZBOKPHAQOMP-SVLSSHOZSA-N

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Description

  • General description: Bis(dibenzylideneacetone)palladium(0) (Pd(dba)2) is an air stable Pd0 complex. It is a reagent for the synthesis of allylic substituted cyclopentadienes.[1] It is a homogeneous catalyst.[2][3] It catalyzes the alkylation of allyl acetates by various nucleophiles under mild conditions.[4]
  • Application: Application Guide for Palladium Catalyzed Cross-Coupling Reactions

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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227994

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form:
powder

Quality Level:
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core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

SMILES string:
[Pd].O=C(/C=C/c1ccccc1)\C=C\c2ccccc2.O=C(/C=C/c3ccccc3)\C=C\c4ccccc4

InChI:
1S/2C17H14O.Pd/c2*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;/h2*1-14H;/b2*13-11+,14-12+;

InChI key:
UKSZBOKPHAQOMP-SVLSSHOZSA-N

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reagent type: oxidant

SMILES string:
[K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O

InChI:
1S/5K.2H2O5S.2H2O4S/c;;;;;2*1-5-6(2,3)4;2*1-5(2,3)4/h;;;;;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5

InChI key:
HJKYXKSLRZKNSI-UHFFFAOYSA-I

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