249491

Tris(4-chlorophenyl)phosphine

95%

Manufacturer: Sigma Aldrich

CAS Number: 1159-54-2

Synonym(S): NSC 136459, Tris(p-chlorophenyl)phosphine

Select a Size

Pack Size SKU Availability Price
1 G 249491-1-G In Stock ₹ 4,990.33

249491 - 1 G

₹ 4,990.33

In Stock

Quantity

1

Base Price: ₹ 4,990.33

GST (18%): ₹ 898.259

Total Price: ₹ 5,888.589

Quality Level

100

Assay

95%

form

powder

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligandreaction type: Cross Couplings

mp

100-103 °C (lit.)

functional group

phosphine

SMILES string

Clc1ccc(cc1)P(c2ccc(Cl)cc2)c3ccc(Cl)cc3

InChI

1S/C18H12Cl3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H

InChI key

IQKSLJOIKWOGIZ-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-242-6142
eMolecules​ Ambeed / Tris(4-chlorophenyl)phosphine / 1g / 490557174 / A358152 / / 1159-54-2 / MFCD00013639 / 365.620 / C18H12Cl3P
eMolecules​ ₹ 2,153.55
50-180-3848
Sigma Aldrich Fine Chemicals Biosciences Tris(4-chlorophenyl)phosphine 95% | 1159-54-2 | MFCD00013639 | 1G
Sigma Aldrich Fine Chemicals Biosciences ₹ 9,925.82
AA21948
1159-54-2 | Tris(4-chlorophenyl)phosphine
A2B Chem ₹ 427.80 - ₹ 684.48

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Description

  • Application: Catalyst for:Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydesSolvent-free Heck reactionsCocatalyst in:Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagentsRhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenesRhodium-catalyzed hydrogenation reactionsPlatinum-catalyzed allylation reactions

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

249491

95%...


Quality Level:
100

Assay:
95%

form:
powder

reaction suitability:
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligandreaction type: Cross Couplings

mp:
100-103 °C (lit.)

functional group:
phosphine

SMILES string:
Clc1ccc(cc1)P(c2ccc(Cl)cc2)c3ccc(Cl)cc3

InChI:
1S/C18H12Cl3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H

InChI key:
IQKSLJOIKWOGIZ-UHFFFAOYSA-N

Img

Sigma Aldrich

249548

technical grade, 70%...


Quality Level:
200

Assay:
70%

form:
solid

reaction suitability:
__

mp:
__

functional group:
__

SMILES string:
OS(=O)(=O)c1ccc2ccccc2c1

InChI:
1S/C10H8O3S/c11-14(12,13)10-6-5-8-3-1-2-4-9(8)7-10/h1-7H,(H,11,12,13)

InChI key:
KVBGVZZKJNLNJU-UHFFFAOYSA-N

Img

Sigma Aldrich

249572

18 wt. % slurry in xylene: light mi...


Quality Level:
100

Assay:
95% (Purity of contained acetylide)

form:
__

reaction suitability:
__

mp:
__

functional group:
__

SMILES string:
[Na]C#C

InChI:
1S/C2H.Na/c1-2;/h1H;

InChI key:
SLBNQJAGYKQCKI-UHFFFAOYSA-N

Img

Sigma Aldrich

249599

99%...


Quality Level:
100

Assay:
99%

form:
liquid

reaction suitability:
__

mp:
−7.6 °C (lit.)

functional group:
__

SMILES string:
CCCCCCCCOCCCCCCCC

InChI:
1S/C16H34O/c1-3-5-7-9-11-13-15-17-16-14-12-10-8-6-4-2/h3-16H2,1-2H3

InChI key:
__