261939

1,2-Bis(dimethylphosphino)ethane

97%

Manufacturer: Sigma Aldrich

CAS Number: 23936-60-9

Synonym(S): DMPE, Dimethyl-2-(dimethylphosphino)ethylphosphine, Ethylenebis(dimethylphosphine)

Select a Size

Pack Size SKU Availability Price
1 G 261939-1-G In Stock ₹ 13,715.28
5 G 261939-5-G In Stock ₹ 52,739.40

261939 - 1 G

₹ 13,715.28

In Stock

Quantity

1

Base Price: ₹ 13,715.28

GST (18%): ₹ 2,468.75

Total Price: ₹ 16,184.03

Quality Level

100

Assay

97%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

refractive index

n20/D 1.507 (lit.)

bp

180 °C (lit.)

density

0.9 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

CP(C)CCP(C)C

InChI

1S/C6H16P2/c1-7(2)5-6-8(3)4/h5-6H2,1-4H3

Other Options

Image Product Name Manufacturer Price Range
50-901-09710
Strem, An Ascensus Company CAS# 23936-60-9. 1g. 1,2-Bis(dimethylphosphino)ethane, 98% DMPE. MFCD00008511
Strem, An Ascensus Company ₹ 18,994.32
50-901-09711
Strem, An Ascensus Company CAS# 23936-60-9. 5g. 1,2-Bis(dimethylphosphino)ethane, 98% DMPE. MFCD00008511
Strem, An Ascensus Company ₹ 63,718.24
AB57066
23936-60-9 | 1,2-bis(Dimethylphosphino)ethane
A2B Chem ₹ 8,641.56 - ₹ 11,465.04

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Description

  • General description: 1,2-Bis(dimethylphosphino)ethane (dmpe) is a polydentate phosphine ligand. Synthesis of 1,2-bis(dimethylphosphino)ethane has been reported.[1] It reacts with ZrCl2 to afford ZrCl4(dmpe)2 complexes.[2]
  • Application: 1,2-Bis(dimethylphosphino)ethane (dmpe) may be employed as ligand in the preparation of cis-arylmethyl(dmpe) nickel(II) complexes.[3]

SAFETY INFORMATION

Pictograms

GHS02,GHS07

Signal Word

Danger

Hazard Statements

H225,H315,H319,H335

Precautionary Statements

P210 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

261939

97%...


Quality Level:
100

Assay:
97%

form:
liquid

reaction suitability:
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

refractive index:
n20/D 1.507 (lit.)

bp:
180 °C (lit.)

density:
0.9 g/mL at 25 °C (lit.)

functional group:
phosphine

SMILES string:
CP(C)CCP(C)C

InChI:
1S/C6H16P2/c1-7(2)5-6-8(3)4/h5-6H2,1-4H3

Img

Sigma Aldrich

261947

98%...


Quality Level:
100

Assay:
98%

form:
solid

reaction suitability:
reagent type: ligandreaction type: Alkylationsreagent type: ligandreaction type: Heck Reactionreagent type: ligandreaction type: Isomerizationsreagent type: ligandreaction type: Negishi Couplingreagent type: ligandreaction type: Sonogashira Couplingreagent type: ligandreaction type: Stille Couplingreagent type: ligandreaction type: Suzuki-Miyaura Coupling

refractive index:
__

bp:
__

density:
__

functional group:
phosphine

SMILES string:
C(CCP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4

InChI:
1S/C28H28P2/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h1-12,15-22H,13-14,23-24H2

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Sigma Aldrich

261955

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Quality Level:
100

Assay:
≥99.9% trace metals basis

form:
powder

reaction suitability:
core: rheniumreagent type: catalyst

refractive index:
__

bp:
360 °C (lit.)

density:
6.103 g/mL at 25 °C (lit.)

functional group:
__

SMILES string:
O=[Re](=O)(=O)O[Re](=O)(=O)=O

InChI:
1S/7O.2Re

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Sigma Aldrich

261963

75-80 wt. % in H2O...


Quality Level:
100

Assay:
__

form:
liquid

reaction suitability:
core: rheniumreagent type: catalyst

refractive index:
__

bp:
__

density:
2.16 g/mL at 25 °C

functional group:
__

SMILES string:
O[Re](=O)(=O)=O

InChI:
1S/H2O.3O.Re/h1H2;;;;/q;;;;+1/p-1