324108

Trimethylphosphine solution

1.0 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 594-09-2

Synonym(S): PMe3, Trimethylphosphorus

Select a Size

Pack Size SKU Availability Price
100 ML 324108-100-ML In Stock ₹ 19,062.83

324108 - 100 ML

₹ 19,062.83

In Stock

Quantity

1

Base Price: ₹ 19,062.83

GST (18%): ₹ 3,431.309

Total Price: ₹ 22,494.139

form

liquid

Quality Level

100

reaction suitability

reagent type: ligandreaction type: Mitsunobu Reactionreagent type: ligandreaction type: Wittig Reaction

concentration

1.0 M in THF

density

0.872 g/mL at 25 °C

functional group

phosphine

SMILES string

CP(C)C

InChI

1S/C3H9P/c1-4(2)3/h1-3H3

InChI key

YWWDBCBWQNCYNR-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-183-7352
Sigma Aldrich Fine Chemicals Biosciences Trimethylphosphine solution, 1.0 M in toluene | 594-09-2 | MFCD00008510 | 100ml
Sigma Aldrich Fine Chemicals Biosciences ₹ 24,945.02
50-183-7353
Sigma Aldrich Fine Chemicals Biosciences Trimethylphosphine solution 1.0 M in 2-methyltetrahydrofuran | 594-09-2 | MFCD00008510 | 25ML
Sigma Aldrich Fine Chemicals Biosciences ₹ 13,730.67
323322
Trimethylphosphine
Sigma Aldrich ₹ 46,774.83
324116
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Sigma Aldrich ₹ 18,900.45
901443
Trimethylphosphine solution
Sigma Aldrich ₹ 8,844.03
AB80095
594-09-2 | Trimethylphosphine
A2B Chem ₹ 18,823.20 - ₹ 47,742.48

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Description

  • General description: Trimethylphosphine is the reagent used in Mitsunobu reaction. It participates in the transformation of azides into carbamates, aziridines from azidoalcohols, iminophosphoranes and aza-Wittig reaction. Electron diffraction study of trimethylphosphine has been reported.[1]
  • Application: Trimethylphosphine (PMe3) solution is the suitable reagent used in the synthesis of Fe/Te cluster type complex, Fe6Te8(PMe3)6.[2] It may be employed as a probe to investigate the acid sites in Y-zeolite.[3] It may be used for the synthesis of hexakis(trimethylphosphine)tris-μ-methylene-diruthenium(III).[4]

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS07

Signal Word

Danger

Hazard Statements

H225,H302,H315,H319,H335,H336,H351

Precautionary Statements

P202 - P210 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

WGK

WGK 3

Flash Point(F)

-22.0 °F

Flash Point(C)

-30 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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liquid

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reaction suitability:
reagent type: ligandreaction type: Mitsunobu Reactionreagent type: ligandreaction type: Wittig Reaction

concentration:
1.0 M in THF

density:
0.872 g/mL at 25 °C

functional group:
phosphine

SMILES string:
CP(C)C

InChI:
1S/C3H9P/c1-4(2)3/h1-3H3

InChI key:
YWWDBCBWQNCYNR-UHFFFAOYSA-N

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SMILES string:
C[C@@H]1Cc2ccc(C(=O)N[C@@H](Cc3ccccc3)C(O)=O)c(O)c2C(=O)O1

InChI:
1S/C20H19NO6/c1-11-9-13-7-8-14(17(22)16(13)20(26)27-11)18(23)21-15(19(24)25)10-12-5-3-2-4-6-12/h2-8,11,15,22H,9-10H2,1H3,(H,21,23)(H,24,25)/t11-,15+/m1/s1

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InChI key:
YWWDBCBWQNCYNR-UHFFFAOYSA-N

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OC(=O)Cc1ccccc1Nc2c(Cl)cc(O)cc2Cl

InChI:
1S/C14H11Cl2NO3/c15-10-6-9(18)7-11(16)14(10)17-12-4-2-1-3-8(12)5-13(19)20/h1-4,6-7,17-18H,5H2,(H,19,20)

InChI key:
__