Home Products Chemistry And Biochemicals Catalysts 324124
SDS
324124

2-Chloro-1,3,2-benzodioxaphosphorin-4-one

95%

Manufacturer: Sigma Aldrich

CAS Number: 5381-99-7

Synonym(S): SalPCl, Salicyl chlorophosphite

Select a Size

Pack Size SKU Availability Price
5 G 324124-5-G In Stock ₹ 2,820.00
25 G 324124-25-G In Stock ₹ 12,890.00

324124 - 5 G

₹ 2,820.00

In Stock

Quantity

1

Base Price: ₹ 2,820.00

GST (18%): ₹ 507.60

Total Price: ₹ 3,327.60

Quality Level

200

Assay

95%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

bp

127-128 °C/11 mmHg (lit.)

mp

36-40 °C (lit.)

functional group

phosphine

storage temp.

2-8°C

SMILES string

ClP1OC(=O)c2ccccc2O1

InChI

1S/C7H4ClO3P/c8-12-10-6-4-2-1-3-5(6)7(9)11-12/h1-4H

Other Options

Image Product Name Manufacturer Price Range
50-180-4012
Sigma Aldrich Fine Chemicals Biosciences 2-Chloro-1,3,2-benzodioxaphosphorin-4-one 95% | 5381-99-7 | MFCD00013353 | 25G
Sigma Aldrich Fine Chemicals Biosciences ₹ 37,103.09
50-180-4013
Sigma Aldrich Fine Chemicals Biosciences 2-Chloro-1,3,2-benzodioxaphosphorin-4-one 95% | 5381-99-7 | MFCD00013353 | 5G
Sigma Aldrich Fine Chemicals Biosciences ₹ 13,730.67
AB61701
5381-99-7 | 2-Chloro-4H-benzo[d][1,3,2]dioxaphosphinin-4-one
A2B Chem --

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Description

  • Application: 2-Chloro-1,3,2-benzodioxaphosphorin-4-one is used as a reagent: In the phosphorylation and phosphitylation of alcohols.[1][2] In the formation of H-phosphonates which are commonly utilized in the synthesis of nucleotides.[1][2] To synthesize nucleoside triphosphates by treating with acyl protected nucleoside.[3]

SAFETY INFORMATION

Pictograms

GHS05

Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Supplementary Hazards

EUH014

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

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Sigma Aldrich

324124

95%...

Quality Level:
200
Assay:
95%
form:
solid
reaction suitability:
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand
bp:
127-128 °C/11 mmHg (lit.)
mp:
36-40 °C (lit.)
functional group:
phosphine
storage temp.:
2-8°C
SMILES string:
ClP1OC(=O)c2ccccc2O1
InChI:
1S/C7H4ClO3P/c8-12-10-6-4-2-1-3-5(6)7(9)11-12/h1-4H

Img

Supelco

32414

VETRANAL®, analytical standard...

Quality Level:
100
Assay:
__
form:
__
reaction suitability:
__
bp:
__
mp:
__
functional group:
__
storage temp.:
2-8°C
SMILES string:
[2H]C([2H])([2H])Oc1cc(Cc2cnc(N)nc2N)cc(OC([2H])([2H])[2H])c1OC([2H])([2H])[2H]
InChI:
__

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Sigma Aldrich

324140

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Quality Level:
100
Assay:
≥95%
form:
liquid
reaction suitability:
__
bp:
90-91 °C/50 mmHg (lit.)
mp:
__
functional group:
__
storage temp.:
2-8°C
SMILES string:
[H]C(=O)\C([H])=C(/[H])CCCC
InChI:
1S/C7H12O/c1-2-3-4-5-6-7-8/h5-7H,2-4H2,1H3/b6-5+

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Supelco

32417

VETRANAL®, analytical standard...

Quality Level:
100
Assay:
__
form:
__
reaction suitability:
__
bp:
__
mp:
__
functional group:
__
storage temp.:
2-8°C
SMILES string:
C[C@@H]1C\C=C\C=C\C=C\C=C\[C@@H](C[C@@H]2O[C@](O)(C[C@@H](O)C[C@H]3O[C@@H]3\C=C\C(=O)O1)C[C@H](O)[C@H]2C(O)=O)O[C@@H]4O[C@H](C)[C@@H](O)[C@H](N)[C@@H]4O
InChI:
1S/C33H47NO13/c1-18-10-8-6-4-3-5-7-9-11-21(45-32-30(39)28(34)29(38)19(2)44-32)15-25-27(31(40)41)22(36)17-33(42,47-25)16-20(35)14-24-23(46-24)12-13-26(37)43-18/h3-9,11-13,18-25,27-30,32,35-36,38-39,42H,10,14-17,34H2,1-2H3,(H,40,41)/b4-3+,7-5+,8-6+,11-9+,13-12+/t18-,19-,20+,21+,22+,23-,24-,25+,27-,28+,29-,30+,32+,33-/m1/s1