328219

[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)

Manufacturer: Sigma Aldrich

CAS Number: 14647-23-5

Synonym(S): 1,2-Ethylenebis(diphenylphosphine)nickel dichloride, Nickel 1,2-Bis(diphenylphosphino)ethane dichloride, [1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride, dppeNiCl2

Select a Size

Pack Size SKU Availability Price
1 G 328219-1-G In Stock ₹ 3,723.80
5 G 328219-5-G In Stock ₹ 10,327.05
25 G 328219-25-G In Stock ₹ 24,745.95

328219 - 1 G

₹ 3,723.80

In Stock

Quantity

1

Base Price: ₹ 3,723.80

GST (18%): ₹ 670.284

Total Price: ₹ 4,394.084

form

solid

Quality Level

100

reaction suitability

core: nickelreagent type: catalyst

mp

263-265 °C (lit.)

SMILES string

Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4

InChI

1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChI key

XXECWTBMGGXMKP-UHFFFAOYSA-L

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Description

  • Application: Reactant involved in:Kumada catalyst-transfer polycondensationOxidation of carboranyl phosphine ligandsSynthesis of nickel-iron dithiolato hydridesUllmann reactions - homocoupling reactionsCo-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centersCatalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes

SAFETY INFORMATION

Pictograms

GHS08,GHS07

Signal Word

Danger

Hazard Statements

H302 + H312 + H332,H315,H319,H334,H335,H350

Precautionary Statements

P202 - P280 - P301 + P312 - P302 + P352 + P312 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

328219

--


form:
solid

Quality Level:
100

reaction suitability:
core: nickelreagent type: catalyst

mp:
263-265 °C (lit.)

SMILES string:
Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4

InChI:
1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChI key:
XXECWTBMGGXMKP-UHFFFAOYSA-L

Img

Supelco

32825

VETRANAL®, analytical standard...


form:
__

Quality Level:
100

reaction suitability:
__

mp:
__

SMILES string:
Cl.CCC(C)(C)NCC(O)c1cc(Cl)c(N)c(Cl)c1

InChI:
1S/C13H20Cl2N2O.ClH/c1-4-13(2,3)17-7-11(18)8-5-9(14)12(16)10(15)6-8;/h5-6,11,17-18H,4,7,16H2,1-3H3;1H

InChI key:
__

Img

Sigma Aldrich

328251

10 wt. % in H2O...


form:
__

Quality Level:
100

reaction suitability:
__

mp:
__

SMILES string:
[OH-].C[N+](C)(C)C

InChI:
1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1

InChI key:
WGTYBPLFGIVFAS-UHFFFAOYSA-M

Img

Sigma Aldrich

328251

10 wt. % in H2O...


form:
__

Quality Level:
100

reaction suitability:
__

mp:
__

SMILES string:
[OH-].C[N+](C)(C)C

InChI:
1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1

InChI key:
WGTYBPLFGIVFAS-UHFFFAOYSA-M