335002

Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

Manufacturer: Sigma Aldrich

CAS Number: 25360-32-1

Synonym(S): Dihydridocarbonyltris(triphenylphosphine)ruthenium

Select a Size

Pack Size SKU Availability Price
1 G 335002-1-G In Stock ₹ 10,589.40

335002 - 1 G

₹ 10,589.40

In Stock

Quantity

1

Base Price: ₹ 10,589.40

GST (18%): ₹ 1,906.092

Total Price: ₹ 12,495.492

Quality Level

100

reaction suitability

core: rutheniumreagent type: catalystreaction type: C-H Activation

mp

161-163 °C (lit.)

SMILES string

[RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI

1S/3C18H15P.CO.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;;;;

InChI key

MLIYPCQSOXNTLJ-UHFFFAOYSA-N

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Description

  • Application: Catalyst for conversion of 1,4-alkynediols into pyrroles Catalyst for oxidation of primary alcohols to methyl esters Catalyst for rearrangement of oximes to amides Catalyst for C-C coupling via directed C-H activation Catalyst for enyne cyclization

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302 + H312 + H332

Precautionary Statements

P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
100

reaction suitability:
core: rutheniumreagent type: catalystreaction type: C-H Activation

mp:
161-163 °C (lit.)

SMILES string:
[RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI:
1S/3C18H15P.CO.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;;;;

InChI key:
MLIYPCQSOXNTLJ-UHFFFAOYSA-N

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