8.14761

Tetrakis(triphenylphosphine)-palladium(0)

for synthesis

Manufacturer: Sigma Aldrich

CAS Number: 14221-01-3

Synonym(S): Tetrakis(triphenylphosphine)-palladium(0)

Select a Size

Pack Size SKU Availability Price
500 MG 8.14761-500-MG In Stock ₹ 5,819.99
1 G 8.14761-1-G In Stock ₹ 8,630.00
5 G 8.14761-5-G In Stock ₹ 25,840.00
25 G 8.14761-25-G In Stock ₹ 89,570.00

8.14761 - 500 MG

₹ 5,819.99

In Stock

Quantity

1

Base Price: ₹ 5,819.99

GST (18%): ₹ 1,047.598

Total Price: ₹ 6,867.588

Quality Level

200

form

powder

reaction suitability

reagent type: catalystreaction type: Cross Couplings

mp

103-107 °C

storage temp.

2-8°C

InChI

1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;

InChI key

NFHFRUOZVGFOOS-UHFFFAOYSA-N

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Description

  • General description: Tetrakis(triphenylphosphine)-palladium(0) can be used to catalyze the formation of carbon-carbon bonds, the reduction of functional groups, the formation of carbon-metal bonds, and the deprotection of allyloxycarbonyl groups[1].
  • Application: Preparation of tricationic tris(pyridylpalladium(II)) metallacyclophane as an anion receptor.: This research explores the synthesis of a tricationic tris(pyridylpalladium(II)) metallacyclophane, showcasing its potential as an anion receptor. The study emphasizes the versatility of palladium complexes in developing new molecular structures for various applications (Danjo et al., 2022).A Ligand-Enabled Palladium-Catalyzed Highly para-Selective Difluoromethylation of Aromatic Ketones.: This study demonstrates the use of a palladium catalyst for highly selective difluoromethylation of aromatic ketones, highlighting the catalyst′s efficiency in organic synthesis and its potential for developing pharmaceuticals (Tu et al., 2018).Viable pathways for the oxidative addition of iodobenzene to palladium(0)-triphenylphosphine-carbonyl complexes: a theoretical study.: This theoretical investigation explores the oxidative addition mechanisms of iodobenzene to palladium(0)-triphenylphosphine-carbonyl complexes, providing insights into the reactivity and applications of palladium catalysts in organic synthesis (Pálinkás et al., 2017).Morita-Baylis-Hillman Reaction of α,β-Unsaturated Ketones with Allylic Acetates by the Combination of Transition-Metal Catalysis and Organomediation.: The paper discusses a novel Morita-Baylis-Hillman reaction facilitated by palladium(0) catalysts, demonstrating its utility in constructing complex molecular architectures for pharmaceutical synthesis (Li et al., 2016).Synthesis of a sterically crowded atropisomeric 1,8-diacridylnaphthalene for dual-mode enantioselective fluorosensing.: This research highlights the synthesis of a novel atropisomeric compound using palladium(0) catalysts, focusing on its application in enantioselective fluorosensing, crucial for biochemical analyses (Mei et al., 2006).
  • Analysis Note: Assay (ICP-OES): ≥ 97.0 %

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302

Precautionary Statements

P264 - P270 - P301 + P312 - P501

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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8.14761

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Quality Level:
200

form:
powder

reaction suitability:
reagent type: catalystreaction type: Cross Couplings

mp:
103-107 °C

storage temp.:
2-8°C

InChI:
1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;

InChI key:
NFHFRUOZVGFOOS-UHFFFAOYSA-N

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Sigma Aldrich

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InChI key:
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Sigma Aldrich

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InChI:
1S/C20H14O2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12,21-22H

InChI key:
PPTXVXKCQZKFBN-UHFFFAOYSA-N