919780

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads

Manufacturer: Sigma Aldrich

CAS Number: 72287-26-4

Synonym(S): Pd(dppf)Cl2

Select a Size

Pack Size SKU Availability Price
250 MG 919780-250-MG In Stock ₹ 12,437.93
1 G 919780-1-G In Stock ₹ 31,089.40

919780 - 250 MG

₹ 12,437.93

In Stock

Quantity

1

Base Price: ₹ 12,437.93

GST (18%): ₹ 2,238.827

Total Price: ₹ 14,676.757

form

solid

Quality Level

100

composition

~ 4 wt.% loading of catalyst

reaction suitability

reagent type: catalystreaction type: Cross Couplings

InChI

1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q2*-1;;;2*+2/p-2

InChI key

NXQGGXCHGDYOHB-UHFFFAOYSA-L

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Description

  • Application: Catalyst for C-C and C-N coupling reaction.Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.[1]Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.[2]Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.[3]ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.Learn more about ChemBeads products For larger scale uses, product also available in powdered form (697230) & (931217)
  • Other Notes: High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass BeadsVersatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput ExperimentationChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

SAFETY INFORMATION

Pictograms

GHS08

Signal Word

Danger

Hazard Statements

H350i

Precautionary Statements

P201 - P202 - P280 - P308 + P313 - P405 - P501

Hazard Classifications

Carc. 1B Inhalation

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Sigma Aldrich

919780

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form:
solid

Quality Level:
100

composition:
~ 4 wt.% loading of catalyst

reaction suitability:
reagent type: catalystreaction type: Cross Couplings

InChI:
1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q2*-1;;;2*+2/p-2

InChI key:
NXQGGXCHGDYOHB-UHFFFAOYSA-L

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Sigma Aldrich

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solid

Quality Level:
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~ 4 wt.% loading of catalyst

reaction suitability:
reagent type: catalystreaction type: Cross Couplings

InChI:
1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChI key:
PIBWKRNGBLPSSY-UHFFFAOYSA-L

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__