(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
97%
Manufacturer: Sigma Aldrich
CAS Number: 38465-86-0
Synonym(S): [Ir(PMePh2)2COD]+ PF6-, [Ir(cod)(PPh2Me)2]PF6, {Ir(COD)[PCH3(C6H5)2]2}PF6
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 50 MG | 337455-50-MG | In Stock | ₹ 2,974.80 |
| 500 MG | 337455-500-MG | In Stock | ₹ 10,223.10 |
337455 - 50 MG
In Stock
Quantity
1
Base Price: ₹ 2,974.80
GST (18%): ₹ 535.464
Total Price: ₹ 3,510.264
Quality Level
100
Assay
97%
reaction suitability
core: iridiumreagent type: catalyst
mp
224 °C (dec.) (lit.)
SMILES string
[Ir+].F[P-](F)(F)(F)(F)F.C1CC=CCCC=C1.CP(c2ccccc2)c3ccccc3.CP(c4ccccc4)c5ccccc5
InChI
1S/2C13H13P.C8H12.F6P.Ir/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;1-7(2,3,4,5)6;/h2*2-11H,1H3;1-2,7-8H,3-6H2;;/q;;;-1;+1/b;;2-1-,8-7-;;
InChI key
LXKHQEQLBSJJCO-JXNOXZOESA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE | Aaron Chemicals LLC | ₹ 4,278.00 - ₹ 28,234.80 | |
 | (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate | ChemScene | ₹ 8,128.20 - ₹ 97,538.40 | |
 | 38465-86-0 | (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate | A2B Chem | ₹ 2,737.92 - ₹ 1,57,173.72 |
Related Products
Description
- Application: (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions.[1] Upon bubbling hydrogen into the solution of [Ir(cod)(PPh2Me)2]PF6, preferably in tetrahydrofuran[2], results in the formation of active catalyst [IrH2(solv)2(PPh2Me)2]PF6 which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters[3]; diallyl ethers to allyl (E)-vinyl ethers[2] and 1-alkenylboronates to corresponding 3-alkoxyallylboronates.[4]
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 97%
reaction suitability: core: iridiumreagent type: catalyst
mp: 224 °C (dec.) (lit.)
SMILES string: [Ir+].F[P-](F)(F)(F)(F)F.C1CC=CCCC=C1.CP(c2ccccc2)c3ccccc3.CP(c4ccccc4)c5ccccc5
InChI: 1S/2C13H13P.C8H12.F6P.Ir/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;1-7(2,3,4,5)6;/h2*2-11H,1H3;1-2,7-8H,3-6H2;;/q;;;-1;+1/b;;2-1-,8-7-;;
InChI key: LXKHQEQLBSJJCO-JXNOXZOESA-N
Quality Level: 100
Assay: __
reaction suitability: __
mp: __
SMILES string: CO\N=C1/C[C@]2(C[C@@H]3CC(C\C=C(C)\C[C@@H](C)\C=C\C=C4/COC5[C@H](O)C(C)=C[C@@H](C(=O)O3)[C@]45O)O2)O[C@@H]([C@H]1C)\C(C)=C\C(C)C
InChI: 1S/C37H53NO8/c1-21(2)14-25(6)33-26(7)31(38-42-8)19-36(46-33)18-29-17-28(45-36)13-12-23(4)15-22(3)10-9-11-27-20-43-34-32(39)24(5)16-30(35(40)44-29)37(27,34)41/h9-12,14,16,21-22,26,28-30,32-34,39,41H,13,15,17-20H2,1-8H3/b10-9+,23-12+,25-14+,27-11+,38-31+/t22-,26-,28+,29-,30-,32+,33+,34+,36-,37+/m0/s1
InChI key: __
Quality Level: 100
Assay: 85%
reaction suitability: core: iridiumreagent type: catalyst
mp: 175 °C (dec.) (lit.)
SMILES string: [Ir+].c1ccncc1.F[P-](F)(F)(F)(F)F.C2CC=CCCC=C2.C3CCC(CC3)P(C4CCCCC4)C5CCCCC5
InChI: 1S/C18H33P.C8H12.C5H5N.F6P.Ir/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-6-8-7-5-3-1;1-2-4-6-5-3-1;1-7(2,3,4,5)6;/h16-18H,1-15H2;1-2,7-8H,3-6H2;1-5H;;/q;;;-1;+1/b;2-1-,8-7-;;;
InChI key: UJXHUUQZACSUOG-KJWGIZLLSA-N
