Home Products Chemistry And Biochemicals Catalysts 338370
SDS
338370

Pentamethylcyclopentadienylrhodium(III) chloride dimer

97%

Manufacturer: Sigma Aldrich

CAS Number: 12354-85-7

Synonym(S): 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex, Bis(dichloro(pentamethylcyclopentadienyl)rhodium), Bis(pentamethylcyclopentadienylrhodium dichloride), Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer, Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium

Select a Size

Pack Size SKU Availability Price
250 MG 338370-250-MG In Stock ₹ 27,239.40
1 G 338370-1-G In Stock ₹ 95,737.50

338370 - 250 MG

₹ 27,239.40

In Stock

Quantity

1

Base Price: ₹ 27,239.40

GST (18%): ₹ 4,903.092

Total Price: ₹ 32,142.492

Quality Level

100

Assay

97%

form

solid

reaction suitability

core: rhodiumreaction type: C-H Activationreagent type: catalystreaction type: C-Mannosylation

SMILES string

Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C

InChI

1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4

InChI key

QNIVKTTWBMFSBR-UHFFFAOYSA-J

Other Options

Image Product Name Manufacturer Price Range
50-246-5778
eMolecules​ AstaTech / PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER / 0.25g / 449765095 / F20614 / 95.000 / 12354-85-7 / [null] / 618.070 / C20H30Cl4Rh2
eMolecules​ ₹ 15,994.59
686891
Chiralyst P618
Sigma Aldrich ₹ 56,643.30 - ₹ 1,26,795.30
CS-0031511
[Rh(Cp-)Cl2]2
ChemScene ₹ 3,080.16 - ₹ 93,174.84

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Description

  • Application: Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bondAmidation reactionsReductive alkylation reactions

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302 + H312 + H332,H315

Precautionary Statements

P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Skin Irrit. 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Show Difference

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Sigma Aldrich

338370

97%...

Quality Level:
100
Assay:
97%
form:
solid
reaction suitability:
core: rhodiumreaction type: C-H Activationreagent type: catalystreaction type: C-Mannosylation
SMILES string:
Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI:
1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key:
QNIVKTTWBMFSBR-UHFFFAOYSA-J

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InChI:
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InChI key:
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Sigma Aldrich

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VETRANAL®, analytical standard...

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form:
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reaction suitability:
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SMILES string:
O[C@H]([C@@H](O)C(O)=O)C(O)=O.CC[C@H]1OC(=O)C[C@@H](O)[C@H](C)[C@@H](O[C@@H]2O[C@H](C)[C@@H](O[C@H]3C[C@@](C)(O)[C@@H](O)[C@H](C)O3)[C@@H]([C@H]2O)N(C)C)[C@@H](CC=O)C[C@@H](C)C(=O)\C=C\C(C)=C\[C@@H]1CO[C@@H]4O[C@H](C)[C@@H](O)[C@@H](OC)[C@H]4OC
InChI:
1S/C46H77NO17.C4H6O6/c1-13-33-30(22-58-45-42(57-12)41(56-11)37(52)26(5)60-45)18-23(2)14-15-31(49)24(3)19-29(16-17-48)39(25(4)32(50)20-34(51)62-33)64-44-38(53)36(47(9)10)40(27(6)61-44)63-35-21-46(8,55)43(54)28(7)59-35;5-1(3(7)8)2(6)4(9)10/h14-15,17-18,24-30,32-33,35-45,50,52-55H,13,16,19-22H2,1-12H3;1-2,5-6H,(H,7,8)(H,9,10)/b15-14+,23-18+;/t24-,25+,26-,27-,28+,29+,30-,32-,33-,35+,36-,37-,38-,39-,40-,41-,42-,43+,44+,45-,46-;1-,2-/m11/s1
InChI key:
__