686891

Chiralyst P618

Umicore

Manufacturer: Sigma Aldrich

CAS Number: 12354-85-7

Synonym(S): Pentamethylcyclopentadienylrhodium(III) chloride dimer, Di(μ-chloro)dichlorobis(pentamethylcyclopentadiene)dirhodium(III), 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex, Bis(dichloro(pentamethylcyclopentadienyl)rhodium), Bis(pentamethylcyclopentadienylrhodium dichloride), Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer, Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium

Select a Size

Pack Size SKU Availability Price
500 MG 686891-500-MG In Stock ₹ 56,643.30
2 G 686891-2-G In Stock ₹ 1,26,795.30

686891 - 500 MG

₹ 56,643.30

In Stock

Quantity

1

Base Price: ₹ 56,643.30

GST (18%): ₹ 10,195.794

Total Price: ₹ 66,839.094

Quality Level

100

form

powder

reaction suitability

core: rhodiumreaction type: Cross Couplingsreagent type: catalystreaction type: C-H Activation

SMILES string

Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C

InChI

1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4

InChI key

QNIVKTTWBMFSBR-UHFFFAOYSA-J

Other Options

Image Product Name Manufacturer Price Range
50-246-5778
eMolecules​ AstaTech / PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER / 0.25g / 449765095 / F20614 / 95.000 / 12354-85-7 / [null] / 618.070 / C20H30Cl4Rh2
eMolecules​ ₹ 15,994.59
338370
Pentamethylcyclopentadienylrhodium(III) chloride dimer
Sigma Aldrich ₹ 27,239.40 - ₹ 95,737.50
CS-0031511
[Rh(Cp-)Cl2]2
ChemScene ₹ 3,080.16 - ₹ 93,174.84

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Description

  • Application: Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bondAmidation reactionsReductive alkylation reactions
  • Legal Information: Product of UmicoreAdditional information available at www.pmc.umicore.com

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302 + H312 + H332,H315

Precautionary Statements

P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Skin Irrit. 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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core: rhodiumreaction type: Cross Couplingsreagent type: catalystreaction type: C-H Activation

SMILES string:
Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C

InChI:
1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4

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QNIVKTTWBMFSBR-UHFFFAOYSA-J

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InChI:
1S/C9H10ClN5O2/c10-8-2-1-7(5-12-8)6-14-4-3-11-9(14)13-15(16)17/h1-2,5H,3-4,6H2,(H,11,13)

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QYDAFWKRBZYBOB-UHFFFAOYSA-N

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Clc1ccc(cc1)-c2cc(nc(c2)-c3ccccn3)-c4ccccn4

InChI:
1S/C21H14ClN3/c22-17-9-7-15(8-10-17)16-13-20(18-5-1-3-11-23-18)25-21(14-16)19-6-2-4-12-24-19/h1-14H

InChI key:
UPOMZZQMFGCHGB-UHFFFAOYSA-N