339768

Tetrakis(acetonitrile)palladium(II) tetrafluoroborate

Manufacturer: Sigma Aldrich

CAS Number: 21797-13-7

Synonym(S): NSC 307191, Palladium(II) tetrafluoroborate tetraacetonitrile complex

Select a Size

Pack Size SKU Availability Price
250 MG 339768-250-MG In Stock ₹ 7,625.70
1 G 339768-1-G In Stock ₹ 21,822.60

339768 - 250 MG

₹ 7,625.70

In Stock

Quantity

1

Base Price: ₹ 7,625.70

GST (18%): ₹ 1,372.626

Total Price: ₹ 8,998.326

form

solid

Quality Level

100

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystcore: palladiumreagent type: ligand

mp

230 °C (dec.) (lit.)

SMILES string

[Pd++].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F.F[B-](F)(F)F

InChI

1S/4C2H3N.2BF4.Pd/c4*1-2-3;2*2-1(3,4)5;/h4*1H3;;;/q;;;;2*-1;+2

InChI key

YWMRPVUMBTVUEX-UHFFFAOYSA-N

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Description

  • General description: Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a stronger Lewis acid.[1] It participates in the preparation of 2:1 complex [Pd(1,2-bis(2′-pyridylethynyl)benzene)2](BF4]2, by Sonogashira cross-coupling reaction.[2]
  • Application: Application Guide for Palladium Catalyzed Cross-Coupling ReactionsReactant involved in:Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligandsPrecursor for:Synthesis of dendritic SCS-pincer palladium complexesPalladium complexes of click ligandsDipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H332

Precautionary Statements

P261 - P271 - P304 + P340 + P312

Hazard Classifications

Acute Tox. 4 Inhalation

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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form:
solid

Quality Level:
100

reaction suitability:
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystcore: palladiumreagent type: ligand

mp:
230 °C (dec.) (lit.)

SMILES string:
[Pd++].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F.F[B-](F)(F)F

InChI:
1S/4C2H3N.2BF4.Pd/c4*1-2-3;2*2-1(3,4)5;/h4*1H3;;;/q;;;;2*-1;+2

InChI key:
YWMRPVUMBTVUEX-UHFFFAOYSA-N

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SMILES string:
O.O.O.O.[Ni++].[Ni++].O[Ni]O.O[Ni]O.O[Ni]O.[O-]C([O-])=O.[O-]C([O-])=O

InChI:
1S/2CH2O3.5Ni.10H2O/c2*2-1(3)4;;;;;;;;;;;;;;;/h2*(H2,2,3,4);;;;;;10*1H2/q;;5*+2;;;;;;;;;;/p-10

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KWOUKTWMXYFKIW-UHFFFAOYSA-D

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