[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
98%
Manufacturer: Sigma Aldrich
CAS Number: 79255-71-3
Synonym(S): [Rh(dppb)(COD)]BF4
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 341134-100-MG | In Stock | ₹ 10,755.90 |
| 500 MG | 341134-500-MG | In Stock | ₹ 38,994.30 |
341134 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 10,755.90
GST (18%): ₹ 1,936.062
Total Price: ₹ 12,691.962
Quality Level
100
Assay
98%
reaction suitability
core: rhodiumreagent type: catalyst
mp
205 °C (dec.) (lit.)
SMILES string
[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C(CCP(c2ccccc2)c3ccccc3)CP(c4ccccc4)c5ccccc5
InChI
1S/C28H28P2.C8H12.BF4.Rh/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-12,15-22H,13-14,23-24H2;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;
InChI key
YESRLRPURJQQBI-ONEVTFJLSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | eMolecules 1,4-Bis(diphenylphosphino)butane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, dichloromethane adduct, min. 98% | 79255-71-3 | MFCD00075219 | 500mg | eMolecules | ₹ 47,769.00 | |
 | [1,4-BIs(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | ChemScene | ₹ 8,470.44 - ₹ 33,282.84 | |
 | 79255-71-3 | [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(i) tetrafluoroborate | A2B Chem | ₹ 11,807.28 - ₹ 37,817.52 |
Related Products
Description
- General description: [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a rhodium-based catalyst used for regioselective hydrogenation and enantioselective reductive amination reactions.
- Application: [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I)tetrafluoroborate can be used as a catalyst for the:Regioselective hydrogenation of thebaine to synthesize tetrahydrothebaine.Enantioselective reductive amination of α-ketoacids with benzylamines to synthesize α-N-benzylamino acids.Stereoselective hydrogenation of α-(hydroxymethyl)-acrylate derivatives to synthesize 3-hydroxy-2-methylpropanoates.
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 98%
reaction suitability: core: rhodiumreagent type: catalyst
mp: 205 °C (dec.) (lit.)
SMILES string: [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C(CCP(c2ccccc2)c3ccccc3)CP(c4ccccc4)c5ccccc5
InChI: 1S/C28H28P2.C8H12.BF4.Rh/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-12,15-22H,13-14,23-24H2;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;
InChI key: YESRLRPURJQQBI-ONEVTFJLSA-N
Quality Level: 100
Assay: __
reaction suitability: reagent type: catalystcore: zinc
mp: __
SMILES string: -
InChI: [Zn]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10
InChI key: 1S/C32H16N8.Zn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2
Quality Level: __
Assay: __
reaction suitability: __
mp: __
SMILES string: __
InChI: __
InChI key: __
