374482
N-Benzylquininium chloride
95%
Manufacturer: Sigma Aldrich
CAS Number: 67174-25-8
Synonym(S): QUIBEC
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 5 G | 374482-5-G | In Stock | ₹ 12,383.80 |
374482 - 5 G
In Stock
Quantity
1
Base Price: ₹ 12,383.80
GST (18%): ₹ 2,229.084
Total Price: ₹ 14,612.884
Quality Level
100
Assay
95%
optical activity
[α]20/D −235°, c = 1.5 in H2O
mp
200-205 °C (dec.) (lit.)
SMILES string
[Cl-].COc1ccc2nccc([C@@H](O)[C@@H]3C[C@@H]4CC[N@+]3(C[C@@H]4C=C)Cc5ccccc5)c2c1
InChI
1S/C27H31N2O2.ClH/c1-3-20-18-29(17-19-7-5-4-6-8-19)14-12-21(20)15-26(29)27(30)23-11-13-28-25-10-9-22(31-2)16-24(23)25;/h3-11,13,16,20-21,26-27,30H,1,12,14-15,17-18H2,2H3;1H/q+1;/p-1/t20-,21-,26-,27+,29+;/m0./s1
InChI key
JYDIJFKNXHPWBJ-GOGFHWEMSA-M
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | eMolecules (-)-N-Benzylquininium chloride | 67174-25-8 | | 1g | eMolecules | ₹ 4,606.55 | |
 | eMolecules ChemScene / N-Benzylquinine (chloride) / 1g / 712788733 / CS-W011581 / 0.000 / 67174-25-8 / [null] / 451.010 / C27H31ClN2O2 | eMolecules | ₹ 2,678.88 | |
 | (2S,4S,5R)-1-Benzyl-2-((R)-hydroxy(6-methoxyquinolin-4-yl)methyl)-5-vinylquinuclidin-1-ium chloride | ChemScene | ₹ 598.92 - ₹ 16,170.84 | |
 | 67174-25-8 | (2S,4S,5R)-1-Benzyl-2-((R)-hydroxy(6-methoxyquinolin-4-yl)methyl)-5-vinylquinuclidin-1-ium chloride | A2B Chem | ₹ 598.92 - ₹ 3,593.52 |
Related Products
Description
- General description: N-Benzylquininium chloride (or Quibec) belongs to the class of cinchona family of alkaloids. It is used as a catalyst in the presence of hydroxide bases in various phase transfer reactions, epoxidations, alkylations, and Michael reactions.[1]
- Application: N-Benzylquininium chloride can be used as a phase transfer catalyst:In the sulfenylation of various β-keto sulfoxides.[2] To synthesize N-carbamoyl-protected β-nitroamines from α-amido sulfones by asymmetric aza-Henry reaction.[3]
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 95%
optical activity: [α]20/D −235°, c = 1.5 in H2O
mp: 200-205 °C (dec.) (lit.)
SMILES string: [Cl-].COc1ccc2nccc([C@@H](O)[C@@H]3C[C@@H]4CC[N@+]3(C[C@@H]4C=C)Cc5ccccc5)c2c1
InChI: 1S/C27H31N2O2.ClH/c1-3-20-18-29(17-19-7-5-4-6-8-19)14-12-21(20)15-26(29)27(30)23-11-13-28-25-10-9-22(31-2)16-24(23)25;/h3-11,13,16,20-21,26-27,30H,1,12,14-15,17-18H2,2H3;1H/q+1;/p-1/t20-,21-,26-,27+,29+;/m0./s1
InChI key: JYDIJFKNXHPWBJ-GOGFHWEMSA-M
Quality Level:
100
Assay:
95%
optical activity:
[α]20/D −235°, c = 1.5 in H2O
mp:
200-205 °C (dec.) (lit.)
SMILES string:
[Cl-].COc1ccc2nccc([C@@H](O)[C@@H]3C[C@@H]4CC[N@+]3(C[C@@H]4C=C)Cc5ccccc5)c2c1
InChI:
1S/C27H31N2O2.ClH/c1-3-20-18-29(17-19-7-5-4-6-8-19)14-12-21(20)15-26(29)27(30)23-11-13-28-25-10-9-22(31-2)16-24(23)25;/h3-11,13,16,20-21,26-27,30H,1,12,14-15,17-18H2,2H3;1H/q+1;/p-1/t20-,21-,26-,27+,29+;/m0./s1
InChI key:
JYDIJFKNXHPWBJ-GOGFHWEMSA-M
Quality Level: 200
Assay: 94%
optical activity: __
mp: __
SMILES string: COC(=O)C(Cl)C(=O)OC
InChI: 1S/C5H7ClO4/c1-9-4(7)3(6)5(8)10-2/h3H,1-2H3
InChI key: LNBQBURECUEBKZ-UHFFFAOYSA-N
Quality Level:
200
Assay:
94%
optical activity:
__
mp:
__
SMILES string:
COC(=O)C(Cl)C(=O)OC
InChI:
1S/C5H7ClO4/c1-9-4(7)3(6)5(8)10-2/h3H,1-2H3
InChI key:
LNBQBURECUEBKZ-UHFFFAOYSA-N
Quality Level: 200
Assay: 96%
optical activity: __
mp: __
SMILES string: COCCC(O)=O
InChI: 1S/C4H8O3/c1-7-3-2-4(5)6/h2-3H2,1H3,(H,5,6)
InChI key: YSIKHBWUBSFBRZ-UHFFFAOYSA-N
Quality Level:
200
Assay:
96%
optical activity:
__
mp:
__
SMILES string:
COCCC(O)=O
InChI:
1S/C4H8O3/c1-7-3-2-4(5)6/h2-3H2,1H3,(H,5,6)
InChI key:
YSIKHBWUBSFBRZ-UHFFFAOYSA-N
Quality Level: __
Assay: 97%
optical activity: __
mp: __
SMILES string: CCCC[Sn](CCCC)(CCCC)c1ccccc1
InChI: 1S/C6H5.3C4H9.Sn/c1-2-4-6-5-3-1;3*1-3-4-2;/h1-5H;3*1,3-4H2,2H3;
InChI key: SYUVAXDZVWPKSI-UHFFFAOYSA-N
Quality Level:
__
Assay:
97%
optical activity:
__
mp:
__
SMILES string:
CCCC[Sn](CCCC)(CCCC)c1ccccc1
InChI:
1S/C6H5.3C4H9.Sn/c1-2-4-6-5-3-1;3*1-3-4-2;/h1-5H;3*1,3-4H2,2H3;
InChI key:
SYUVAXDZVWPKSI-UHFFFAOYSA-N