380768

Potassium diphenylphosphide solution

0.5 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 15475-27-1

Synonym(S): Potassium diphenylphosphine, Diphenylphosphine potassium salt, KPPh2

Select a Size

Pack Size SKU Availability Price
100 ML 380768-100-ML In Stock ₹ 10,846.65
800 ML 380768-800-ML In Stock ₹ 48,138.78

380768 - 100 ML

₹ 10,846.65

In Stock

Quantity

1

Base Price: ₹ 10,846.65

GST (18%): ₹ 1,952.397

Total Price: ₹ 12,799.047

form

liquid

Quality Level

100

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

concentration

0.5 M in THF

density

0.929 g/mL at 25 °C

functional group

phosphine

SMILES string

[K]P(c1ccccc1)c2ccccc2

InChI

1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1

InChI key

FCLYZQXPJKJTDR-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-177-0256
Sigma Aldrich Fine Chemicals Biosciences Potassium diphenylphosphide solution 0.5 M in THF | 15475-27-1 | MFCD00134530 | 800ML
Sigma Aldrich Fine Chemicals Biosciences ₹ 74,206.19

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Description

  • Application: Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.: This study explores the synthesis and reactivity of a novel phosphino complex, utilizing Potassium diphenylphosphide as a key reagent. The research highlights the molecular structure and potential applications in organometallic chemistry (Godoy et al., 2009).Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde.: This paper details an improved synthesis method for chiral N,P-ligands using Potassium diphenylphosphide. The research demonstrates the compound′s efficacy in asymmetric synthesis, offering potential advancements in drug discovery and development (Rönnholm et al., 2007).Coordination chemistry of diselenophosphinate complexes: the X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3].L (L = THF, PhMe).: This article investigates the coordination chemistry involving diselenophosphinate complexes, with Potassium diphenylphosphide playing a crucial role. The study provides detailed X-ray crystallographic data, offering insights for future research in chemical synthesis and materials science (Davies et al., 2004).

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H302,H314,H335,H351

Precautionary Statements

P201 - P210 - P233 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH018,EUH019

WGK

WGK 3

Flash Point(F)

-4.0 °F

Flash Point(C)

-20 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

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Sigma Aldrich

380768

0.5 M in THF...


form:
liquid

Quality Level:
100

reaction suitability:
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

concentration:
0.5 M in THF

density:
0.929 g/mL at 25 °C

functional group:
phosphine

SMILES string:
[K]P(c1ccccc1)c2ccccc2

InChI:
1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1

InChI key:
FCLYZQXPJKJTDR-UHFFFAOYSA-N

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Sigma Aldrich

380776

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form:
liquid

Quality Level:
__

reaction suitability:
__

concentration:
__

density:
1.271 g/mL at 25 °C (lit.)

functional group:
__

SMILES string:
CC(CCl)(CCl)CCl

InChI:
1S/C5H9Cl3/c1-5(2-6,3-7)4-8/h2-4H2,1H3

InChI key:
BYXOMFFBGDPXHB-UHFFFAOYSA-N

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Sigma Aldrich

380806

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form:
liquid

Quality Level:
__

reaction suitability:
__

concentration:
__

density:
0.999 g/mL at 25 °C (lit.)

functional group:
__

SMILES string:
CC(C)(C)c1ccc(cc1)C(=O)OC=C

InChI:
1S/C13H16O2/c1-5-15-12(14)10-6-8-11(9-7-10)13(2,3)4/h5-9H,1H2,2-4H3

InChI key:
ZLHVSEPPILCZHH-UHFFFAOYSA-N

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Sigma Aldrich

380814

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form:
liquid

Quality Level:
100

reaction suitability:
__

concentration:
7.2-8.5% P2O5 (by NaOH, titration)

density:
1.5 g/mL at 25 °C

functional group:
__

SMILES string:
CS(O)(=O)=O.O=P(=O)OP(=O)=O

InChI:
1S/CH4O3S.O5P2/c1-5(2,3)4;1-6(2)5-7(3)4/h1H3,(H,2,3,4);

InChI key:
JHNLZOVBAQWGQU-UHFFFAOYSA-N