401595

4-(Diphenylphosphino)benzoic acid

97%

Manufacturer: Sigma Aldrich

CAS Number: 2129-31-9

Synonym(S): (4-Carboxyphenyl)diphenylphosphine, Diphenyl(p-carboxyphenyl) phosphine, p-(Diphenylphosphino)benzoic acid

Select a Size

Pack Size SKU Availability Price
1 G 401595-1-G In Stock ₹ 6,354.28
5 G 401595-5-G In Stock ₹ 21,671.65

401595 - 1 G

₹ 6,354.28

In Stock

Quantity

1

Base Price: ₹ 6,354.28

GST (18%): ₹ 1,143.77

Total Price: ₹ 7,498.05

Quality Level

100

Assay

97%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

mp

157-160 °C (lit.)

functional group

phosphine

SMILES string

OC(=O)c1ccc(cc1)P(c2ccccc2)c3ccccc3

InChI

1S/C19H15O2P/c20-19(21)15-11-13-18(14-12-15)22(16-7-3-1-4-8-16)17-9-5-2-6-10-17/h1-14H,(H,20,21)

InChI key

GXMHDTPYKRTARV-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-176-0523
Sigma Aldrich Fine Chemicals Biosciences 4-(Diphenylphosphino)benzoic acid 97% | 2129-31-9 | MFCD00407264 | 5G
Sigma Aldrich Fine Chemicals Biosciences ₹ 22,115.55
50-176-0522
Sigma Aldrich Fine Chemicals Biosciences 4-(Diphenylphosphino)benzoic acid 97% | 2129-31-9 | MFCD00407264 | 1G
Sigma Aldrich Fine Chemicals Biosciences ₹ 10,229.55
AB65981
2129-31-9 | 4-(Diphenylphosphino)benzoic acid
A2B Chem ₹ 513.36 - ₹ 12,235.08

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Description

  • General description: 4-(Diphenylphosphino)benzoic acid is a phosphine ligand that is employed in palladium-catalyzed cross-coupling and Suzuki cross-coupling reactions.[1] [2]
  • Application: 4-(Diphenylphosphino)benzoic acid can be used as a ligand in the synthesis of:Organostannoxane-supported palladium nanoparticles. The resulting catalysts show high activity and selectivity in Suzuki-coupling reactions.[3]Polymetallic ruthenium-zinc complex catalyst for the hydrogenation of levulinic acid to γ-valerolactone.[4]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

mp:
157-160 °C (lit.)

functional group:
phosphine

SMILES string:
OC(=O)c1ccc(cc1)P(c2ccccc2)c3ccccc3

InChI:
1S/C19H15O2P/c20-19(21)15-11-13-18(14-12-15)22(16-7-3-1-4-8-16)17-9-5-2-6-10-17/h1-14H,(H,20,21)

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GXMHDTPYKRTARV-UHFFFAOYSA-N

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YVQNEQKKLNWXEM-UHFFFAOYSA-L

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