(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
98%
Manufacturer: Sigma Aldrich
CAS Number: 135616-36-3
Synonym(S): (S,S)-Jacobsen’s ligand
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 5 G | 404438-5-G | In Stock | ₹ 23,197.98 |
404438 - 5 G
In Stock
Quantity
1
Base Price: ₹ 23,197.98
GST (18%): ₹ 4,175.636
Total Price: ₹ 27,373.616
Quality Level
100
Assay
98%
optical activity
[α]20/D +315 to 15°, c = 1 in methylene chloride
mp
203-206 °C (lit.)
SMILES string
CC(C)(C)c1cc(\C=N\[C@H]2CCCC[C@@H]2\N=C\c3cc(cc(c3O)C(C)(C)C)C(C)(C)C)c(O)c(c1)C(C)(C)C
InChI
1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,39-40H,13-16H2,1-12H3/b37-21+,38-22+/t29-,30-/m0/s1
InChI key
FYNXDGNCEBQLGC-GTHUDTLPSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Strem, An Ascensus Company CAS# 135616-36-3. 1g. (1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene), 98% (S,S)-Jacobsen Ligand. MFCD00191801 | Strem, An Ascensus Company | ₹ 4,158.22 | |
 | Strem, An Ascensus Company CAS# 135616-36-3. 5g. (1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene), 98% (S,S)-Jacobsen Ligand. MFCD00191801 | Strem, An Ascensus Company | ₹ 14,066.06 | |
 | eMolecules (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine | 135616-36-3 | | 1g | eMolecules | ₹ 2,073.97 | |
 | 135616-36-3 | (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine | A2B Chem | ₹ 941.16 - ₹ 6,844.80 |
Related Products
Description
- Application: (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine is a chiral salen-type ligand used for preparing Jacobsen′s catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.[1][2][3]
- Legal Information: Licensed through Research Corporation Technologies
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 98%
optical activity: [α]20/D +315 to 15°, c = 1 in methylene chloride
mp: 203-206 °C (lit.)
SMILES string: CC(C)(C)c1cc(\C=N\[C@H]2CCCC[C@@H]2\N=C\c3cc(cc(c3O)C(C)(C)C)C(C)(C)C)c(O)c(c1)C(C)(C)C
InChI: 1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,39-40H,13-16H2,1-12H3/b37-21+,38-22+/t29-,30-/m0/s1
InChI key: FYNXDGNCEBQLGC-GTHUDTLPSA-N
Quality Level: 200
Assay: __
optical activity: __
mp: 330-332 °C (lit.)
SMILES string: CC(C)(C)c1cc2\C=N\[C@@H]3CCCC[C@H]3\N=C\c4cc(cc(c4O[Mn](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI: 1S/C36H54N2O2.ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m1../s1
InChI key: LJVAWOSDJSQANR-OHRASPNLSA-K
Quality Level: 200
Assay: __
optical activity: __
mp: 330-332 °C (lit.)
SMILES string: CC(C)(C)c1cc2C=[N@@H]3[C@H]4CCCC[C@@H]4[N@H]5=Cc6cc(cc(c6O[Mn]35(Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI: 1S/C36H54N2O2.ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1
InChI key: LJVAWOSDJSQANR-RUIQGICGSA-K
