(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
Manufacturer: Sigma Aldrich
CAS Number: 135620-04-1
Synonym(S): (S,S)-Jacobsen’s catalyst
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 404454-1-G | In Stock | ₹ 4,546.50 |
| 5 G | 404454-5-G | In Stock | ₹ 20,383.48 |
| 25 G | 404454-25-G | In Stock | ₹ 36,891.60 |
404454 - 1 G
In Stock
Quantity
1
Base Price: ₹ 4,546.50
GST (18%): ₹ 818.37
Total Price: ₹ 5,364.87
Quality Level
200
mp
330-332 °C (lit.)
SMILES string
CC(C)(C)c1cc2C=[N@@H]3[C@H]4CCCC[C@@H]4[N@H]5=Cc6cc(cc(c6O[Mn]35(Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI
1S/C36H54N2O2.ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1
InChI key
LJVAWOSDJSQANR-RUIQGICGSA-K
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride | 135620-04-1 | MFCD02101663 | 25G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 68,956.23 | |
 | Sigma Aldrich Fine Chemicals Biosciences (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride | 135620-04-1 | MFCD02101663 | 5G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 20,228.95 | |
 | eMolecules ChemScene / (SS)-[NN-Bis(35-di-tert-butylsalicylidene)-12-cyclohexanediamine]manganese(III) chloride / 10g / 536856876 / CS-W013785 / 0.000 / 135620-04-1 / [null] / 665.280 / C38H58ClMnN2O2 | eMolecules | ₹ 4,343.88 |
Related Products
Description
- General description: (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a metal-salen complex that can catalyze a variety of asymmetric transformations.
- Application: Reactant involved in:Studies of intercalative binding with ct-DNA and radical scavenging antioxidant activityImmobilization on phenoxy-modified zirconium poly(styrenephenylvinylphosphonate) Synthesis of derivatvies for studies of conformational models of enantioselective reactionsCatalyst involved in:Asymmetric epoxidation of olefinsImmobilization on ionic liquid modified mesoporous silica for oxidative kinetic resolution of racemic secondary alcohols†Immobilization on diamine modified zirconium olig-styrenyl phosphonate hydrogen phosphate for epoxidation of styrene
- Legal Information: Manufactured under license by Sterling Pharma Solutions Limited, using Jacobsen HKR technology.
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 200
mp: 330-332 °C (lit.)
SMILES string: CC(C)(C)c1cc2C=[N@@H]3[C@H]4CCCC[C@@H]4[N@H]5=Cc6cc(cc(c6O[Mn]35(Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI: 1S/C36H54N2O2.ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1
InChI key: LJVAWOSDJSQANR-RUIQGICGSA-K
Quality Level: 100
mp: 248-252 °C (lit.)
SMILES string: Oc1ccc2ccccc2c1N=Nc3ccc(cc3)[N+]([O-])=O
InChI: 1S/C16H11N3O3/c20-15-10-5-11-3-1-2-4-14(11)16(15)18-17-12-6-8-13(9-7-12)19(21)22/h1-10,20H
InChI key: WOTPFVNWMLFMFW-UHFFFAOYSA-N
Quality Level: __
mp: __
SMILES string: __
InChI: 1S/C9H13NO/c1-4-10-7(2)5-9(6-11)8(10)3/h5-6H,4H2,1-3H3
InChI key: __
