457701

(S)-(−)-2-Methyl-CBS-oxazaborolidine solution

1 M in toluene

Manufacturer: Sigma Aldrich

CAS Number: 112022-81-8

Synonym(S): α,α-Diphenyl-L-prolinol methylboronic acid cycl-amide ester, (S)-1-Methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2c][1,3,2]oxazaborole, (S)-3,3-Diphenyl-1-methyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole, (S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole

Select a Size

Pack Size SKU Availability Price
5 ML 457701-5-ML In Stock ₹ 6,819.75
25 ML 457701-25-ML In Stock ₹ 23,457.78

457701 - 5 ML

₹ 6,819.75

In Stock

Quantity

1

Base Price: ₹ 6,819.75

GST (18%): ₹ 1,227.555

Total Price: ₹ 8,047.305

Quality Level

100

concentration

1 M in toluene

bp

111 °C

density

0.929 g/mL at 25 °C

storage temp.

room temp

SMILES string

CB1OC([C@@H]2CCCN12)(c3ccccc3)c4ccccc4

InChI

1S/C18H20BNO/c1-19-20-14-8-13-17(20)18(21-19,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17H,8,13-14H2,1H3/t17-/m0/s1

InChI key

VMKAFJQFKBASMU-KRWDZBQOSA-N

Other Options

Image Product Name Manufacturer Price Range
50-901-08717
Strem, An Ascensus Company CAS# 112022-81-8. 10ml. (S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, 0.9-1.1M in toluene [(S)-Methyloxazaborolidine] (S)-CBS Catalyst. MFCD00078439
Strem, An Ascensus Company ₹ 12,423.31
NC2593979
Ambeed (S)-2-Methyl-CBS-oxazaborolidine | 112022-81-8 | 277.2 g/mol | 25G
Ambeed ₹ 22,138.65
649309
(S)-(−)-2-Methyl-CBS-oxazaborolidine
Sigma Aldrich ₹ 8,681.65 - ₹ 47,413.50
674648
(S)-(−)-2-Methyl-CBS-oxazaborolidine solution
Sigma Aldrich ₹ 11,268.83 - ₹ 24,399.55
AR0032WO
(S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole
Aaron Chemicals LLC ₹ 342.24 - ₹ 37,304.16
AB42636
112022-81-8 | (S)-2-Methyl-CBS-oxazaborolidine
A2B Chem ₹ 1,454.52 - ₹ 19,251.00

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Description

  • Application: CBS Catalysts for Asymmetric Reduction and Asymmetric Synthesis
  • Other Notes: Precipitate may form in storage, but does not affect product quality. Gently heat product to 80-90 °C under an inert atmosphere to redissolve solids.

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H302,H304,H315,H318,H336,H361d,H373,H412

Precautionary Statements

P201 - P210 - P273 - P280 - P301 + P310 + P331 - P305 + P351 + P338 + P310

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

Target Organs

Central nervous system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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1 M in toluene

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0.929 g/mL at 25 °C

storage temp.:
room temp

SMILES string:
CB1OC([C@@H]2CCCN12)(c3ccccc3)c4ccccc4

InChI:
1S/C18H20BNO/c1-19-20-14-8-13-17(20)18(21-19,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17H,8,13-14H2,1H3/t17-/m0/s1

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VMKAFJQFKBASMU-KRWDZBQOSA-N

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c1ccc2c(c1)sc3ccccc23

InChI:
1S/C12H8S/c1-3-7-11-9(5-1)10-6-2-4-8-12(10)13-11/h1-8H

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