633305

Bismuth(III) trifluoromethanesulfonate

Manufacturer: Sigma Aldrich

CAS Number: 88189-03-1

Synonym(S): Bi(OTf)3, Bismuth tris(trifluoromethanesulfonate), Bismuth(III) triflate

Select a Size

Pack Size SKU Availability Price
5 G 633305-5-G In Stock ₹ 9,930.00
25 G 633305-25-G In Stock ₹ 28,854.25

633305 - 5 G

₹ 9,930.00

In Stock

Quantity

1

Base Price: ₹ 9,930.00

GST (18%): ₹ 1,787.40

Total Price: ₹ 11,717.40

Quality Level

100

reaction suitability

core: bismuthreagent type: catalyst

mp

>300 °C (lit.)

SMILES string

[Bi+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/3CHF3O3S.Bi/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3

InChI key

NYENCOMLZDQKNH-UHFFFAOYSA-K

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Description

  • Application: Bismuth(III) trifluoromethanesulfonate may be used as a catalyst in the following processes:[1]deprotection of acetals cleavage of 2-tert-butoxy derivatives of thiophenes and furansallylation of acetals to form homoallyl ethersIt may also be used as a substitute to corrosive triflic acid in Friedel-Crafts (FC) acylation and sulfonylation of arenes.[2]
  • Packaging: Bismuth(III) trifluoromethanesulfonate is an eco-friendly Lewis acid that can be prepared by reacting triflic acid with bismuth(III) trifluoroacetate.[4]

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
100

reaction suitability:
core: bismuthreagent type: catalyst

mp:
>300 °C (lit.)

SMILES string:
[Bi+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI:
1S/3CHF3O3S.Bi/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3

InChI key:
NYENCOMLZDQKNH-UHFFFAOYSA-K

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1S/C8H15BO2/c1-6-9-10-7(2,3)8(4,5)11-9/h6H,1H2,2-5H3

InChI key:
DPGSPRJLAZGUBQ-UHFFFAOYSA-N

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