734527

Tetrakis(pyridine)copper(II) triflate

95%

Manufacturer: Sigma Aldrich

CAS Number: 113110-58-0

Synonym(S): [Cu(OTf)2(py)4], Cu(pyridine)4(OTf)2, Tetrakis(pyridine)copper(II) bis(trifluoromethanesulfonate)

Select a Size

Pack Size SKU Availability Price
250 MG 734527-250-MG In Stock ₹ 7,057.90
1 G 734527-1-G In Stock ₹ 19,571.60

734527 - 250 MG

₹ 7,057.90

In Stock

Quantity

1

Base Price: ₹ 7,057.90

GST (18%): ₹ 1,270.422

Total Price: ₹ 8,328.322

Quality Level

100

Assay

95%

form

crystals

reaction suitability

core: copperreagent type: catalyst

mp

190-194 °C

storage temp.

−20°C

SMILES string

c1ccncc1.c2ccncc2.c3ccncc3.c4ccncc4.FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F

InChI

1S/4C5H5N.2CHF3O3S.Cu/c4*1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;/h4*1-5H;2*(H,5,6,7);/q;;;;;;+2/p-2

InChI key

DOUMBTAZXRQKGF-UHFFFAOYSA-L

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Description

  • Application: Tetrakis(pyridine)copper(II) triflate [Cu(OTf)2(py)4] is a general copper-based catalyst.[1] It is commonly used to catalyze copper-mediated radiofluorination of arenes and heteroarene.[2][3][4] It is also employed in C(sp3)-H functionalization/cyclisation of 2-amino-N,N-dialkylbenzamides to synthesize 2,3-disubstituted-4(3H)-quinazolinones.[5]

SAFETY INFORMATION

Pictograms

GHS05

Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Quality Level:
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Assay:
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crystals

reaction suitability:
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mp:
190-194 °C

storage temp.:
−20°C

SMILES string:
c1ccncc1.c2ccncc2.c3ccncc3.c4ccncc4.FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F

InChI:
1S/4C5H5N.2CHF3O3S.Cu/c4*1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;/h4*1-5H;2*(H,5,6,7);/q;;;;;;+2/p-2

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DOUMBTAZXRQKGF-UHFFFAOYSA-L

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LJZVDOUZSMHXJH-UHFFFAOYSA-K

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QXDYJUSFCUKOQD-UHFFFAOYSA-N

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SCCOCCOCCOCCOCCOCCS

InChI:
__

InChI key:
__