665096

Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)

97%

Manufacturer: Sigma Aldrich

CAS Number: 108695-90-5

Synonym(S): Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium

Select a Size

Pack Size SKU Availability Price
250 MG 665096-250-MG In Stock ₹ 4,838.78
1 G 665096-1-G In Stock ₹ 16,616.38

665096 - 250 MG

₹ 4,838.78

In Stock

Quantity

1

Base Price: ₹ 4,838.78

GST (18%): ₹ 870.98

Total Price: ₹ 5,709.76

Quality Level

100

Assay

97%

form

powder

reaction suitability

core: rheniumreagent type: catalyst

SMILES string

CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3

InChI key

GIBDGLAUIKUJJX-UHFFFAOYSA-K

Other Options

Image Product Name Manufacturer Price Range
AE28039
108695-90-5 | OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V)
A2B Chem ₹ 13,946.28

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Description

  • Application: Catalyst for:Enantioselective reduction of ketones and iminesMeyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compoundsSynthesis of 2-deoxy-α glycosidesSulfurization of phosphorous(III) compounds with thiiranesReactant for synthesis of mono and dinuclear compoundsReagent for rhenium-cyclized somatostatine derivative series synthesis

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

665096

97%...


Quality Level:
100

Assay:
97%

form:
powder

reaction suitability:
core: rheniumreagent type: catalyst

SMILES string:
CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3

InChI:
1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3

InChI key:
GIBDGLAUIKUJJX-UHFFFAOYSA-K

Img

Sigma Aldrich

665118

97%...


Quality Level:
100

Assay:
97%

form:
solid

reaction suitability:
reaction type: solution phase peptide synthesis

SMILES string:
COc1ccc(N)c(c1)C(O)=O

InChI:
1S/C8H9NO3/c1-12-5-2-3-7(9)6(4-5)8(10)11/h2-4H,9H2,1H3,(H,10,11)

InChI key:
UMKSAURFQFUULT-UHFFFAOYSA-N

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Sigma Aldrich

665142

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Quality Level:
100

Assay:
__

form:
solid

reaction suitability:
core: goldreagent type: catalyst

SMILES string:
[Au][O+]([Au])[Au].F[B-](F)(F)F.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI:
1S/3C18H15P.3Au.BF4.O/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;2-1(3,4)5;/h3*1-15H;;;;;/q;;;;;;-1;+1

InChI key:
HTZIGJMQHZNAQD-UHFFFAOYSA-N

Img

Sigma Aldrich

665177

99%...


Quality Level:
100

Assay:
99%

form:
solid

reaction suitability:
core: goldreagent type: catalyst

SMILES string:
Cl[Au].FC(F)(F)c1ccc(cc1)P(c2ccc(cc2)C(F)(F)F)c3ccc(cc3)C(F)(F)F

InChI:
1S/C21H12F9P.Au.ClH/c22-19(23,24)13-1-7-16(8-2-13)31(17-9-3-14(4-10-17)20(25,26)27)18-11-5-15(6-12-18)21(28,29)30;;/h1-12H;;1H/q;+1;/p-1

InChI key:
UNHMCLFZEQKHCQ-UHFFFAOYSA-M