676004

(R)-(+)-2,2′,6,6′-Tetramethoxy-4,4′-bis(di(3,5-xylyl)phosphino)-3,3′-bipyridine

97%

Manufacturer: Sigma Aldrich

CAS Number: 442905-33-1

Synonym(S): (R)-Xylyl-P-Phos

Select a Size

Pack Size SKU Availability Price
100 MG 676004-100-MG In Stock ₹ 9,536.83

676004 - 100 MG

₹ 9,536.83

In Stock

Quantity

1

Base Price: ₹ 9,536.83

GST (18%): ₹ 1,716.629

Total Price: ₹ 11,253.459

Quality Level

100

Assay

97%

form

solid

optical activity

[α]20/D +125°, c = 1 in chloroform

mp

190-194 °C

SMILES string

COc1cc(P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3)c(c(OC)n1)-c4c(OC)nc(OC)cc4P(c5cc(C)cc(C)c5)c6cc(C)cc(C)c6

InChI

1S/C46H50N2O4P2/c1-27-13-28(2)18-35(17-27)53(36-19-29(3)14-30(4)20-36)39-25-41(49-9)47-45(51-11)43(39)44-40(26-42(50-10)48-46(44)52-12)54(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38/h13-26H,1-12H3

InChI key

JRTHAKOHBMETRC-UHFFFAOYSA-N

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Description

  • Application: Ligand employed in the asymmetic hydrogenation of ß-keto esters, 2-arylacrylates, aryl ketones , and other substrates.[1]
  • Legal Information: Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US5886182 and any patents arising therefrom apply.

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

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Sigma Aldrich

676004

97%...


Quality Level:
100

Assay:
97%

form:
solid

optical activity:
[α]20/D +125°, c = 1 in chloroform

mp:
190-194 °C

SMILES string:
COc1cc(P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3)c(c(OC)n1)-c4c(OC)nc(OC)cc4P(c5cc(C)cc(C)c5)c6cc(C)cc(C)c6

InChI:
1S/C46H50N2O4P2/c1-27-13-28(2)18-35(17-27)53(36-19-29(3)14-30(4)20-36)39-25-41(49-9)47-45(51-11)43(39)44-40(26-42(50-10)48-46(44)52-12)54(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38/h13-26H,1-12H3

InChI key:
JRTHAKOHBMETRC-UHFFFAOYSA-N

Img

Sigma Aldrich

676098

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Assay:
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form:
__

optical activity:
[α]20/D -314°, c = 1 in chloroform

mp:
199-203 °C

SMILES string:
Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6

InChI:
1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H

InChI key:
NDTDVKKGYBULHF-UHFFFAOYSA-N

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C(Nc1ncnc2nc[nH]c12)c3ccccc3

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__

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__

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