675806
(R)-(+)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine
97%
Manufacturer: Sigma Aldrich
CAS Number: 221012-82-4
Synonym(S): (R)-P-Phos
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 675806-100-MG | In Stock | ₹ 8,941.45 |
675806 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 8,941.45
GST (18%): ₹ 1,609.461
Total Price: ₹ 10,550.911
Quality Level
100
Assay
97%
form
solid
optical activity
[α]20/D +98°, c = 1 in chloroform
mp
261-265 °C
SMILES string
COc1cc(P(c2ccccc2)c3ccccc3)c(c(OC)n1)-c4c(OC)nc(OC)cc4P(c5ccccc5)c6ccccc6
InChI
1S/C38H34N2O4P2/c1-41-33-25-31(45(27-17-9-5-10-18-27)28-19-11-6-12-20-28)35(37(39-33)43-3)36-32(26-34(42-2)40-38(36)44-4)46(29-21-13-7-14-22-29)30-23-15-8-16-24-30/h5-26H,1-4H3
InChI key
JZOSBBLJKXSBBN-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Strem, An Ascensus Company CAS# 221012-82-4. 100mg. (R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine, min. 97% CTH-(R)-P-Phos. MFCD04038734 | Strem, An Ascensus Company | ₹ 8,111.09 | |
 | (R)-(+)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine | Aaron Chemicals LLC | ₹ 4,620.24 - ₹ 7,785.96 | |
 | 221012-82-4 | (R)-(+)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine | A2B Chem | ₹ 1,796.76 - ₹ 4,876.92 |
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Description
- Application: Ligand employed in the asymmetic hydrogenation of ß-keto esters, 2-arylacrylates, aryl ketones , and other substrates.[1]
- Legal Information: Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US5886182 and any patents arising therefrom apply.
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 97%
form: solid
optical activity: [α]20/D +98°, c = 1 in chloroform
mp: 261-265 °C
SMILES string: COc1cc(P(c2ccccc2)c3ccccc3)c(c(OC)n1)-c4c(OC)nc(OC)cc4P(c5ccccc5)c6ccccc6
InChI: 1S/C38H34N2O4P2/c1-41-33-25-31(45(27-17-9-5-10-18-27)28-19-11-6-12-20-28)35(37(39-33)43-3)36-32(26-34(42-2)40-38(36)44-4)46(29-21-13-7-14-22-29)30-23-15-8-16-24-30/h5-26H,1-4H3
InChI key: JZOSBBLJKXSBBN-UHFFFAOYSA-N
Quality Level:
100
Assay:
97%
form:
solid
optical activity:
[α]20/D +98°, c = 1 in chloroform
mp:
261-265 °C
SMILES string:
COc1cc(P(c2ccccc2)c3ccccc3)c(c(OC)n1)-c4c(OC)nc(OC)cc4P(c5ccccc5)c6ccccc6
InChI:
1S/C38H34N2O4P2/c1-41-33-25-31(45(27-17-9-5-10-18-27)28-19-11-6-12-20-28)35(37(39-33)43-3)36-32(26-34(42-2)40-38(36)44-4)46(29-21-13-7-14-22-29)30-23-15-8-16-24-30/h5-26H,1-4H3
InChI key:
JZOSBBLJKXSBBN-UHFFFAOYSA-N
Quality Level: 100
Assay: 97%
form: solid
optical activity: __
mp: 34-38 °C
SMILES string: COc1cc(Br)cc(Br)c1
InChI: 1S/C7H6Br2O/c1-10-7-3-5(8)2-6(9)4-7/h2-4H,1H3
InChI key: OQZAQBGJENJMHT-UHFFFAOYSA-N
Quality Level:
100
Assay:
97%
form:
solid
optical activity:
__
mp:
34-38 °C
SMILES string:
COc1cc(Br)cc(Br)c1
InChI:
1S/C7H6Br2O/c1-10-7-3-5(8)2-6(9)4-7/h2-4H,1H3
InChI key:
OQZAQBGJENJMHT-UHFFFAOYSA-N
Quality Level: 100
Assay: ≥95.0%
form: solid
optical activity: __
mp: 289-293 °C
SMILES string: CS(=O)(=O)c1ccc(cc1)B(O)O
InChI: 1S/C7H9BO4S/c1-13(11,12)7-4-2-6(3-5-7)8(9)10/h2-5,9-10H,1H3
InChI key: VDUKDQTYMWUSAC-UHFFFAOYSA-N
Quality Level:
100
Assay:
≥95.0%
form:
solid
optical activity:
__
mp:
289-293 °C
SMILES string:
CS(=O)(=O)c1ccc(cc1)B(O)O
InChI:
1S/C7H9BO4S/c1-13(11,12)7-4-2-6(3-5-7)8(9)10/h2-5,9-10H,1H3
InChI key:
VDUKDQTYMWUSAC-UHFFFAOYSA-N
Quality Level: 100
Assay: ≥95%
form: solid
optical activity: __
mp: 84-94 °C85-90 °C (lit.)
SMILES string: CC(C)(C)OC(=O)n1c(cc2ccccc12)B(O)O
InChI: 1S/C13H16BNO4/c1-13(2,3)19-12(16)15-10-7-5-4-6-9(10)8-11(15)14(17)18/h4-8,17-18H,1-3H3
InChI key: SVIBPSNFXYUOFT-UHFFFAOYSA-N
Quality Level:
100
Assay:
≥95%
form:
solid
optical activity:
__
mp:
84-94 °C85-90 °C (lit.)
SMILES string:
CC(C)(C)OC(=O)n1c(cc2ccccc12)B(O)O
InChI:
1S/C13H16BNO4/c1-13(2,3)19-12(16)15-10-7-5-4-6-9(10)8-11(15)14(17)18/h4-8,17-18H,1-3H3
InChI key:
SVIBPSNFXYUOFT-UHFFFAOYSA-N