675156

(R)-VANOL

97%

Manufacturer: Sigma Aldrich

CAS Number: 147702-13-4

Synonym(S): (R)-3,3′-Diphenyl-2,2′-bi-1-naphthalol, (R)-3,3′-Diphenyl-2,2′-bi-1-naphthol

Select a Size

Pack Size SKU Availability Price
250 MG 675156-250-MG In Stock ₹ 12,253.90

675156 - 250 MG

₹ 12,253.90

In Stock

Quantity

1

Base Price: ₹ 12,253.90

GST (18%): ₹ 2,205.702

Total Price: ₹ 14,459.602

Quality Level

100

Assay

97%

form

solid

optical activity

[α]20/D +310°, c = 1 in chloroform

mp

200-204 °C

SMILES string

Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6

InChI

1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H

InChI key

NDTDVKKGYBULHF-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-901-09216
Strem, An Ascensus Company CAS# 147702-13-4. 500mg. (2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol, min. 98% (R)-VANOL. MFCD08459338
Strem, An Ascensus Company ₹ 87,339.65
50-174-5819
Sigma Aldrich Fine Chemicals Biosciences (R)-VANOL 97% | 147702-13-4 | MFCD08459338 | 250MG
Sigma Aldrich Fine Chemicals Biosciences ₹ 19,180.84
AA66058
147702-13-4 | (2R)-3,3'-Diphenyl[2,2'-binaphthalene]-1,1'-diol
A2B Chem ₹ 3,422.40 - ₹ 1,08,062.28

Related Products

Img

Sigma Aldrich

676098

97%...

Img

Sigma Aldrich

675210

97%...

Img

Sigma Aldrich

675334

97%...

Img

Sigma Aldrich

665355

97%...

Img

Sigma Aldrich

675806

97%...

Img

Sigma Aldrich

675792

97%...

Img

Sigma Aldrich

682136

96%...

Img

Sigma Aldrich

697753

95%...

Description

  • Application: (R)-VANOL is a vaulted biaryl ligand that may be used in the following processes:Transformation of 3-substituted cyclobutanones to enantiopure γ-butyrolactones via asymmetric Baeyer-Villiger Reaction in the presence of an aluminum catalyst.[1]Asymmetric aziridination of N-(4-(Methylsulfonyl)benzylidene)diphenylmethanamine to form (2S,3S)-ethyl 1-benzhydryl-3-(4-(methylsulfonyl)phenyl) aziridine-2-carboxylate.[2]Conjugate addition of terminal alkynes to 2-arylidene-1,3-diketones with high enantioselectivity in the presence of diethyl zinc.[3]

SAFETY INFORMATION

Pictograms

GHS05,GHS07

Signal Word

Danger

Hazard Statements

H315,H318,H335,H413

Precautionary Statements

P273 - P280 - P302 + P352 - P305 + P351 + P338 + P310

Hazard Classifications

Aquatic Chronic 4 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

675156

97%...


Quality Level:
100

Assay:
97%

form:
solid

optical activity:
[α]20/D +310°, c = 1 in chloroform

mp:
200-204 °C

SMILES string:
Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6

InChI:
1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H

InChI key:
NDTDVKKGYBULHF-UHFFFAOYSA-N

Img

Sigma Aldrich

67520

≥98.0% (TLC), for peptide synthesis...


Quality Level:
100

Assay:
≥98.0% (TLC)

form:
powder

optical activity:
[α]20/D −24±1°, c = 2% in H2O

mp:
~240 °C (dec.) (lit.)

SMILES string:
Cn1cnc(C[C@H](N)C(O)=O)c1

InChI:
__

InChI key:
__

Img

Sigma Aldrich

675202

--


Quality Level:
100

Assay:
__

form:
solid

optical activity:
__

mp:
233-235 °C

SMILES string:
C12=NCCCN1CCCN2[W-]3([Cl+][W-](N4C5=NCCCN5CCC4)(N6C7=NCCCN7CCC6)[Cl+]3)N8C9=NCCCN9CCC8

InChI:
1S/4C7H12N3.2Cl.2W/c4*1-3-8-7-9-4-2-6-10(7)5-1;;;;/h4*1-6H2;;;;/q4*-1;4*+1

InChI key:
ULSLYQPHFUUSFQ-UHFFFAOYSA-N

Img

Fischer Scientific

6752049

The Vacuum Pump V-100 is a chemical...


Quality Level:
__

Assay:
__

form:
__

optical activity:
__

mp:
__

SMILES string:
__

InChI:
__

InChI key:
__