682136
(S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane
96%
Manufacturer: Sigma Aldrich
CAS Number: 192463-40-4
Synonym(S): (S)-Phanephos
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 500 MG | 682136-500-MG | In Stock | ₹ 55,066.78 |
682136 - 500 MG
In Stock
Quantity
1
Base Price: ₹ 55,066.78
GST (18%): ₹ 9,912.02
Total Price: ₹ 64,978.80
Quality Level
100
Assay
96%
form
solid
optical activity
[α]22/D +34°, c = 1 in chloroform
mp
224-226 °C
SMILES string
C1Cc2ccc(CCc3ccc1cc3P(c4ccccc4)c5ccccc5)cc2P(c6ccccc6)c7ccccc7
InChI
1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2
InChI key
GYZZZILPVUYAFJ-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences (S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane 96% | 192463-40-4 | MFCD03094575 | 500MG | Sigma Aldrich Fine Chemicals Biosciences | ₹ 74,144.12 | |
 | 192463-40-4 | (R)-Phanephos | A2B Chem | ₹ 4,984.00 - ₹ 9,790.00 |
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Description
- Application: Efficient ligand for asymmetric hydrogentation of dehydroamino acids, methyl esters and keytones.[1][2]
- Legal Information: Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US5874629 and any patents arising therefrom apply.
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 96%
form: solid
optical activity: [α]22/D +34°, c = 1 in chloroform
mp: 224-226 °C
SMILES string: C1Cc2ccc(CCc3ccc1cc3P(c4ccccc4)c5ccccc5)cc2P(c6ccccc6)c7ccccc7
InChI: 1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2
InChI key: GYZZZILPVUYAFJ-UHFFFAOYSA-N
Quality Level:
100
Assay:
96%
form:
solid
optical activity:
[α]22/D +34°, c = 1 in chloroform
mp:
224-226 °C
SMILES string:
C1Cc2ccc(CCc3ccc1cc3P(c4ccccc4)c5ccccc5)cc2P(c6ccccc6)c7ccccc7
InChI:
1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2
InChI key:
GYZZZILPVUYAFJ-UHFFFAOYSA-N
Quality Level: 100
Assay: 96%
form: solid
optical activity: [α]/D -34±4°, c = 1 in chloroform
mp: 222-226 °C
SMILES string: __
InChI: 1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2
InChI key: GYZZZILPVUYAFJ-UHFFFAOYSA-N
Quality Level:
100
Assay:
96%
form:
solid
optical activity:
[α]/D -34±4°, c = 1 in chloroform
mp:
222-226 °C
SMILES string:
__
InChI:
1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2
InChI key:
GYZZZILPVUYAFJ-UHFFFAOYSA-N
Quality Level: 100
Assay: 97%
form: solid
optical activity: __
mp: 38-42 °C
SMILES string: Cc1cccc(CBr)n1
InChI: 1S/C7H8BrN/c1-6-3-2-4-7(5-8)9-6/h2-4H,5H2,1H3
InChI key: WJFDCFHWFHCLIW-UHFFFAOYSA-N
Quality Level:
100
Assay:
97%
form:
solid
optical activity:
__
mp:
38-42 °C
SMILES string:
Cc1cccc(CBr)n1
InChI:
1S/C7H8BrN/c1-6-3-2-4-7(5-8)9-6/h2-4H,5H2,1H3
InChI key:
WJFDCFHWFHCLIW-UHFFFAOYSA-N
Quality Level: 100
Assay: 97%
form: solid
optical activity: __
mp: >300 °C
SMILES string: [Cl-].Cc1cc(C)c(c(C)c1)-[n+]2cc3cccc(C)n3c2
InChI: 1S/C17H19N2.ClH/c1-12-8-13(2)17(14(3)9-12)18-10-16-7-5-6-15(4)19(16)11-18;/h5-11H,1-4H3;1H/q+1;/p-1
InChI key: DJFXURXZOPNPGY-UHFFFAOYSA-M
Quality Level:
100
Assay:
97%
form:
solid
optical activity:
__
mp:
>300 °C
SMILES string:
[Cl-].Cc1cc(C)c(c(C)c1)-[n+]2cc3cccc(C)n3c2
InChI:
1S/C17H19N2.ClH/c1-12-8-13(2)17(14(3)9-12)18-10-16-7-5-6-15(4)19(16)11-18;/h5-11H,1-4H3;1H/q+1;/p-1
InChI key:
DJFXURXZOPNPGY-UHFFFAOYSA-M