700665
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
Manufacturer: Sigma Aldrich
CAS Number: 864943-22-6
Synonym(S): (R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 700665-100-MG | In Stock | ₹ 25,038.23 |
700665 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 25,038.23
GST (18%): ₹ 4,506.881
Total Price: ₹ 29,545.111
form
solid
Quality Level
100
optical activity
[α]22/D −44.0°, c = 1 in DMSO
mp
390-400 °C
storage temp.
−20°C
SMILES string
OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)-c6cc7ccccc7c8ccccc68)-c9cc%10ccccc%10c%11ccccc9%11
InChI
1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50)
InChI key
BVICVEIKBNVROI-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-oxide | 864943-22-6 | MFCD12546016 | 100MG | Sigma Aldrich Fine Chemicals Biosciences | ₹ 28,508.59 | |
 | 864943-22-6 | (11Br)-2,6-di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-oxide | A2B Chem | ₹ 5,133.60 - ₹ 2,02,434.96 |
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Description
- Application: Catalyst for:Asymmetric hydrogenation cascadeEnantioselective Friedel-Crafts reactionAsymmetric hydrogenation of 2-substituted quinolinesChiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamatesPreparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/estersAsymmetric transfer hydrogenation of substituted quinoxalines
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
form: solid
Quality Level: 100
optical activity: [α]22/D −44.0°, c = 1 in DMSO
mp: 390-400 °C
storage temp.: −20°C
SMILES string: OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)-c6cc7ccccc7c8ccccc68)-c9cc%10ccccc%10c%11ccccc9%11
InChI: 1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50)
InChI key: BVICVEIKBNVROI-UHFFFAOYSA-N
form:
solid
Quality Level:
100
optical activity:
[α]22/D −44.0°, c = 1 in DMSO
mp:
390-400 °C
storage temp.:
−20°C
SMILES string:
OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)-c6cc7ccccc7c8ccccc68)-c9cc%10ccccc%10c%11ccccc9%11
InChI:
1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50)
InChI key:
BVICVEIKBNVROI-UHFFFAOYSA-N
form: powder
Quality Level: 100
optical activity: [α]22/D +62°, c = 1 in chloroform
mp: 192-202 °C
storage temp.: −20°C
SMILES string: Oc1c(cc2ccccc2c1-c3c(O)c(cc4ccccc34)-c5cc6ccccc6c7ccccc57)-c8cc9ccccc9c%10ccccc8%10
InChI: 1S/C48H30O2/c49-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)50)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28,49-50H
InChI key: XYUOTCUHTHQCNC-UHFFFAOYSA-N
form:
powder
Quality Level:
100
optical activity:
[α]22/D +62°, c = 1 in chloroform
mp:
192-202 °C
storage temp.:
−20°C
SMILES string:
Oc1c(cc2ccccc2c1-c3c(O)c(cc4ccccc34)-c5cc6ccccc6c7ccccc57)-c8cc9ccccc9c%10ccccc8%10
InChI:
1S/C48H30O2/c49-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)50)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28,49-50H
InChI key:
XYUOTCUHTHQCNC-UHFFFAOYSA-N
form: liquid
Quality Level: 100
optical activity: __
mp: __
storage temp.: −20°C
SMILES string: CC(C)C(N(OC(C)c1ccccc1)C(C)(C)C)c2ccccc2
InChI: 1S/C22H31NO/c1-17(2)21(20-15-11-8-12-16-20)23(22(4,5)6)24-18(3)19-13-9-7-10-14-19/h7-18,21H,1-6H3
InChI key: FPFRTDOMIFBPBZ-UHFFFAOYSA-N
form:
liquid
Quality Level:
100
optical activity:
__
mp:
__
storage temp.:
−20°C
SMILES string:
CC(C)C(N(OC(C)c1ccccc1)C(C)(C)C)c2ccccc2
InChI:
1S/C22H31NO/c1-17(2)21(20-15-11-8-12-16-20)23(22(4,5)6)24-18(3)19-13-9-7-10-14-19/h7-18,21H,1-6H3
InChI key:
FPFRTDOMIFBPBZ-UHFFFAOYSA-N
form: solid
Quality Level: 100
optical activity: __
mp: 182 °C (dec.) (lit.)
storage temp.: __
SMILES string: [K+].[K+].[K+].[H]O[H].[H]O[H].OC(=O)CN(CCN(CC([O-])=O)CC([O-])=O)CC([O-])=O
InChI: 1S/C10H16N2O8.3K.2H2O/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20;;;;;/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20);;;;2*1H2/q;3*+1;;/p-3
InChI key: MAPFUJCWRWFQIY-UHFFFAOYSA-K
form:
solid
Quality Level:
100
optical activity:
__
mp:
182 °C (dec.) (lit.)
storage temp.:
__
SMILES string:
[K+].[K+].[K+].[H]O[H].[H]O[H].OC(=O)CN(CCN(CC([O-])=O)CC([O-])=O)CC([O-])=O
InChI:
1S/C10H16N2O8.3K.2H2O/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20;;;;;/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20);;;;2*1H2/q;3*+1;;/p-3
InChI key:
MAPFUJCWRWFQIY-UHFFFAOYSA-K