(S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
96%
Manufacturer: Sigma Aldrich
CAS Number: 929097-92-7
Synonym(S): (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d1′,2′f]-[1,3,2]-dioxaphosphepin 4-oxide, MacMillan TiPSY catalyst
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 680184-100-MG | In Stock | ₹ 30,569.80 |
680184 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 30,569.80
GST (18%): ₹ 5,502.564
Total Price: ₹ 36,072.364
Quality Level
100
Assay
96%
form
solid
optical activity
[α]22/D +210°, c = 1 in chloroform
mp
188-193 °C
SMILES string
OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)[Si](c6ccccc6)(c7ccccc7)c8ccccc8)[Si](c9ccccc9)(c%10ccccc%10)c%11ccccc%11
InChI
1S/C56H41O4PSi2/c57-61(58)59-55-51(62(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)60-61)63(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40H,(H,57,58)
InChI key
BDQOCXQVIFQJRK-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | 929097-92-7 | (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide | A2B Chem | ₹ 1,796.76 - ₹ 17,710.92 |
Related Products
Description
- Application: (S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate can be used as a catalyst:In the synthesis of 1,3-dioxolochroman skeletons by reacting 3-methyl-2-vinylindoles with ortho-quinone methides.[1]In the exo-selective cyclization of mupirocin methyl ester.[2]In the kinetic resolution of cyclic aliphatic syn-1,3-diols, which are used as valuable building blocks.[3]
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 96%
form: solid
optical activity: [α]22/D +210°, c = 1 in chloroform
mp: 188-193 °C
SMILES string: OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)[Si](c6ccccc6)(c7ccccc7)c8ccccc8)[Si](c9ccccc9)(c%10ccccc%10)c%11ccccc%11
InChI: 1S/C56H41O4PSi2/c57-61(58)59-55-51(62(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)60-61)63(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40H,(H,57,58)
InChI key: BDQOCXQVIFQJRK-UHFFFAOYSA-N
Quality Level: 100
Assay: 96%
form: __
optical activity: [α]/D -121 to -113°, c = 1% in chloroform
mp: __
SMILES string: CC(C)[C@H]1COC(=N1)C(C)(C)C2=N[C@H](CO2)C(C)C
InChI: 1S/C15H26N2O2/c1-9(2)11-7-18-13(16-11)15(5,6)14-17-12(8-19-14)10(3)4/h9-12H,7-8H2,1-6H3/t11-,12-/m1/s1
InChI key: XFZUPCITFHSROM-VXGBXAGGSA-N
Quality Level: 100
Assay: 97%
form: __
optical activity: __
mp: __
SMILES string: CC1(C)OB(OC1(C)C)\C=C\CCl
InChI: 1S/C9H16BClO2/c1-8(2)9(3,4)13-10(12-8)6-5-7-11/h5-6H,7H2,1-4H3/b6-5+
InChI key: HLBDNUSUVDDICF-AATRIKPKSA-N
