674737
(R)-3,3′-Bis(triphenylsilyl)-1,1′-bi-2-naphthol
96%
Manufacturer: Sigma Aldrich
CAS Number: 111822-69-6
Synonym(S): (R)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthalene-2,2′-diol
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 674737-100-MG | In Stock | ₹ 16,421.53 |
674737 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 16,421.53
GST (18%): ₹ 2,955.875
Total Price: ₹ 19,377.405
Quality Level
100
Assay
96%
form
solid
optical activity
[α]20/D +114°, c = 1 in chloroform
mp
103-145 °C
SMILES string
Oc1c(cc2ccccc2c1-c3c(O)c(cc4ccccc34)[Si](c5ccccc5)(c6ccccc6)c7ccccc7)[Si](c8ccccc8)(c9ccccc9)c%10ccccc%10
InChI
1S/C56H42O2Si2/c57-55-51(59(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)58)60(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40,57-58H
InChI key
STBZSRVMGWTCOU-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | eMolecules Ambeed / (R)-33-Bis(triphenylsilyl)-[11-binaphthalene]-22-diol / 50mg / 600841822 / A498626 / / 111822-69-6 / MFCD09265078 / 803.120 / C56H42O2Si2 | eMolecules | ₹ 3,730.42 | |
| | Sigma Aldrich Fine Chemicals Biosciences (R)-3,3'-Bis(triphenylsilyl)-1,1'-bi-2-naphthol 96% | 111822-69-6 | MFCD09265078 | 100MG | Sigma Aldrich Fine Chemicals Biosciences | ₹ 28,298.97 | |
 | 111822-69-6 | (R)-3,3′-Bis(triphenylsilyl)-1,1′-bi-2-naphthol | A2B Chem | ₹ 1,796.76 - ₹ 17,710.92 |
Related Products
Description
- Application: (R)-3,3′-Bis(triphenylsilyl)-1,1′-bi-2-naphthol reacts with trimethylaluminum to form a chiral organoaluminum reagent, which can catalyze the asymmetric Diels-Alder reaction of cyclopentadiene and methyl acrylate to form the corresponding Diels-Alder adduct.[1]
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 96%
form: solid
optical activity: [α]20/D +114°, c = 1 in chloroform
mp: 103-145 °C
SMILES string: Oc1c(cc2ccccc2c1-c3c(O)c(cc4ccccc34)[Si](c5ccccc5)(c6ccccc6)c7ccccc7)[Si](c8ccccc8)(c9ccccc9)c%10ccccc%10
InChI: 1S/C56H42O2Si2/c57-55-51(59(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)58)60(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40,57-58H
InChI key: STBZSRVMGWTCOU-UHFFFAOYSA-N
Quality Level:
100
Assay:
96%
form:
solid
optical activity:
[α]20/D +114°, c = 1 in chloroform
mp:
103-145 °C
SMILES string:
Oc1c(cc2ccccc2c1-c3c(O)c(cc4ccccc34)[Si](c5ccccc5)(c6ccccc6)c7ccccc7)[Si](c8ccccc8)(c9ccccc9)c%10ccccc%10
InChI:
1S/C56H42O2Si2/c57-55-51(59(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)58)60(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40,57-58H
InChI key:
STBZSRVMGWTCOU-UHFFFAOYSA-N
Quality Level: 100
Assay: 95%
form: solid
optical activity: [α]22/D -197°, c = 1 in chloroform
mp: 329-335 °C
SMILES string: OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)[Si](c6ccccc6)(c7ccccc7)c8ccccc8)[Si](c9ccccc9)(c%10ccccc%10)c%11ccccc%11
InChI: 1S/C56H41O4PSi2/c57-61(58)59-55-51(62(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)60-61)63(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40H,(H,57,58)
InChI key: BDQOCXQVIFQJRK-UHFFFAOYSA-N
Quality Level:
100
Assay:
95%
form:
solid
optical activity:
[α]22/D -197°, c = 1 in chloroform
mp:
329-335 °C
SMILES string:
OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)[Si](c6ccccc6)(c7ccccc7)c8ccccc8)[Si](c9ccccc9)(c%10ccccc%10)c%11ccccc%11
InChI:
1S/C56H41O4PSi2/c57-61(58)59-55-51(62(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)60-61)63(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40H,(H,57,58)
InChI key:
BDQOCXQVIFQJRK-UHFFFAOYSA-N
Quality Level: 200
Assay: 99.999% trace metals basis
form: powdersolid
optical activity: __
mp: 190-193 °C (lit.)
SMILES string: CC(=O)\C=C(\C)O[Al](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O
InChI: 1S/3C5H8O2.Al/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
InChI key: KILURZWTCGSYRE-LNTINUHCSA-K
Quality Level:
200
Assay:
99.999% trace metals basis
form:
powdersolid
optical activity:
__
mp:
190-193 °C (lit.)
SMILES string:
CC(=O)\C=C(\C)O[Al](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O
InChI:
1S/3C5H8O2.Al/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
InChI key:
KILURZWTCGSYRE-LNTINUHCSA-K
Quality Level: 100
Assay: 97%
form: __
optical activity: __
mp: __
SMILES string: C[C@@H]1CN(CCN1)C(=O)OC(C)(C)C
InChI: 1S/C10H20N2O2/c1-8-7-12(6-5-11-8)9(13)14-10(2,3)4/h8,11H,5-7H2,1-4H3/t8-/m1/s1
InChI key: FMLPQHJYUZTHQS-MRVPVSSYSA-N
Quality Level:
100
Assay:
97%
form:
__
optical activity:
__
mp:
__
SMILES string:
C[C@@H]1CN(CCN1)C(=O)OC(C)(C)C
InChI:
1S/C10H20N2O2/c1-8-7-12(6-5-11-8)9(13)14-10(2,3)4/h8,11H,5-7H2,1-4H3/t8-/m1/s1
InChI key:
FMLPQHJYUZTHQS-MRVPVSSYSA-N