682977

(11bR,11′bR)-4,4′-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis-dinaphtho[2,1-d:1′, 2′-f][1,3,2]dioxaphosphepin

Manufacturer: Sigma Aldrich

CAS Number: 349114-63-2

Synonym(S): R, R-Reetz X-Diphosphonite

Select a Size

Pack Size SKU Availability Price
100 MG 682977-100-MG In Stock ₹ 6,646.55

682977 - 100 MG

₹ 6,646.55

In Stock

Quantity

1

Base Price: ₹ 6,646.55

GST (18%): ₹ 1,196.379

Total Price: ₹ 7,842.929

form

solid

Quality Level

100

optical activity

[α]22/D +270°, c = 1 in chloroform

mp

198-217 °C

SMILES string

CC1(C)c2cccc(P3Oc4ccc5ccccc5c4-c6c(O3)ccc7ccccc67)c2Oc8c(cccc18)P9Oc%10ccc%11ccccc%11c%10-c%12c(O9)ccc%13ccccc%12%13

InChI

1S/C55H36O5P2/c1-55(2)41-21-11-23-47(61-57-43-29-25-33-13-3-7-17-37(33)49(43)50-38-18-8-4-14-34(38)26-30-44(50)58-61)53(41)56-54-42(55)22-12-24-48(54)62-59-45-31-27-35-15-5-9-19-39(35)51(45)52-40-20-10-6-16-36(40)28-32-46(52)60-62/h3-32H,1-2H3

InChI key

DXZANFKSPAISOB-UHFFFAOYSA-N

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Description

  • Application: This diphosphonite ligand has been successfully employed in Noyori-type asymmetric transfer hydrogenation of prochiral ketones.[1]

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable