682977
(11bR,11′bR)-4,4′-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis-dinaphtho[2,1-d:1′, 2′-f][1,3,2]dioxaphosphepin
Manufacturer: Sigma Aldrich
CAS Number: 349114-63-2
Synonym(S): R, R-Reetz X-Diphosphonite
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 682977-100-MG | In Stock | ₹ 6,646.55 |
682977 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 6,646.55
GST (18%): ₹ 1,196.379
Total Price: ₹ 7,842.929
form
solid
Quality Level
100
optical activity
[α]22/D +270°, c = 1 in chloroform
mp
198-217 °C
SMILES string
CC1(C)c2cccc(P3Oc4ccc5ccccc5c4-c6c(O3)ccc7ccccc67)c2Oc8c(cccc18)P9Oc%10ccc%11ccccc%11c%10-c%12c(O9)ccc%13ccccc%12%13
InChI
1S/C55H36O5P2/c1-55(2)41-21-11-23-47(61-57-43-29-25-33-13-3-7-17-37(33)49(43)50-38-18-8-4-14-34(38)26-30-44(50)58-61)53(41)56-54-42(55)22-12-24-48(54)62-59-45-31-27-35-15-5-9-19-39(35)51(45)52-40-20-10-6-16-36(40)28-32-46(52)60-62/h3-32H,1-2H3
InChI key
DXZANFKSPAISOB-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences (11bR,11'bR)-4,4'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis-dinaphtho[2,1-d:1', 2'-f][1,3,2]dioxaphosphepin | 349114-63-2 | MFCD09842740 | 100MG | Sigma Aldrich Fine Chemicals Biosciences | ₹ 13,521.05 | |
 | 349114-63-2 | (11bR,11′bR)-4,4′-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis-dinaphtho[2,1-d:1′, 2′-f][1,3,2]dioxaphosphepin | A2B Chem | -- |
Related Products
Description
- Application: This diphosphonite ligand has been successfully employed in Noyori-type asymmetric transfer hydrogenation of prochiral ketones.[1]
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
Show Difference
form: solid
Quality Level: 100
optical activity: [α]22/D +270°, c = 1 in chloroform
mp: 198-217 °C
SMILES string: CC1(C)c2cccc(P3Oc4ccc5ccccc5c4-c6c(O3)ccc7ccccc67)c2Oc8c(cccc18)P9Oc%10ccc%11ccccc%11c%10-c%12c(O9)ccc%13ccccc%12%13
InChI: 1S/C55H36O5P2/c1-55(2)41-21-11-23-47(61-57-43-29-25-33-13-3-7-17-37(33)49(43)50-38-18-8-4-14-34(38)26-30-44(50)58-61)53(41)56-54-42(55)22-12-24-48(54)62-59-45-31-27-35-15-5-9-19-39(35)51(45)52-40-20-10-6-16-36(40)28-32-46(52)60-62/h3-32H,1-2H3
InChI key: DXZANFKSPAISOB-UHFFFAOYSA-N
form:
solid
Quality Level:
100
optical activity:
[α]22/D +270°, c = 1 in chloroform
mp:
198-217 °C
SMILES string:
CC1(C)c2cccc(P3Oc4ccc5ccccc5c4-c6c(O3)ccc7ccccc67)c2Oc8c(cccc18)P9Oc%10ccc%11ccccc%11c%10-c%12c(O9)ccc%13ccccc%12%13
InChI:
1S/C55H36O5P2/c1-55(2)41-21-11-23-47(61-57-43-29-25-33-13-3-7-17-37(33)49(43)50-38-18-8-4-14-34(38)26-30-44(50)58-61)53(41)56-54-42(55)22-12-24-48(54)62-59-45-31-27-35-15-5-9-19-39(35)51(45)52-40-20-10-6-16-36(40)28-32-46(52)60-62/h3-32H,1-2H3
InChI key:
DXZANFKSPAISOB-UHFFFAOYSA-N
form: __
Quality Level: 100
optical activity: [α]/D 144±4°, c = 0.1 in H2O
mp: __
SMILES string: [Na+].C[C@]2(Cn1ccnn1)[C@@H](N3[C@@H](CC3=O)S2(=O)=O)C([O-])=O
InChI: 1S/C10H12N4O5S.Na/c1-10(5-13-3-2-11-12-13)8(9(16)17)14-6(15)4-7(14)20(10,18)19;/h2-3,7-8H,4-5H2,1H3,(H,16,17);/q;+1/p-1/t7-,8+,10+;/m1./s1
InChI key: __
form:
__
Quality Level:
100
optical activity:
[α]/D 144±4°, c = 0.1 in H2O
mp:
__
SMILES string:
[Na+].C[C@]2(Cn1ccnn1)[C@@H](N3[C@@H](CC3=O)S2(=O)=O)C([O-])=O
InChI:
1S/C10H12N4O5S.Na/c1-10(5-13-3-2-11-12-13)8(9(16)17)14-6(15)4-7(14)20(10,18)19;/h2-3,7-8H,4-5H2,1H3,(H,16,17);/q;+1/p-1/t7-,8+,10+;/m1./s1
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