704628
R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
96%
Manufacturer: Sigma Aldrich
Synonym(S): (R)-TCFP-Rh, TCFP, R-[Rh cod TCFP]BF4
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 704628-100-MG | In Stock | ₹ 22,422.00 |
704628 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 22,422.00
GST (18%): ₹ 4,035.96
Total Price: ₹ 26,457.96
Quality Level
100
Assay
96%
form
solid
mp
171-177 °C
storage temp.
2-8°C
SMILES string
[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CP(CP(C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI
1S/C14H32P2.C8H12.BF4.Rh/c1-12(2,3)15(10)11-16(13(4,5)6)14(7,8)9;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11H2,1-10H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t15-;;;/m1.../s1
InChI key
CQCAQRWECWCUBU-JMJDVLNDSA-N
Related Products
Description
- Application: R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can be used:In the asymmetric reduction of amines, ketones and unsaturated acids.[1][2][3]As a hydrogenation catalyst in the preparation of diastereomers of trifluorovaline.[4]As a catalyst in the olefin asymmetric hydrogenation.[5]
- Legal Information: Sold in collaboration with Johnson Matthey for research purposes only.
SAFETY INFORMATION
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves