704628
R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
96%
Manufacturer: Sigma Aldrich
Synonym(S): (R)-TCFP-Rh, TCFP, R-[Rh cod TCFP]BF4
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 704628-100-MG | In Stock | ₹ 22,422.00 |
704628 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 22,422.00
GST (18%): ₹ 4,035.96
Total Price: ₹ 26,457.96
Quality Level
100
Assay
96%
form
solid
mp
171-177 °C
storage temp.
2-8°C
SMILES string
[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CP(CP(C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI
1S/C14H32P2.C8H12.BF4.Rh/c1-12(2,3)15(10)11-16(13(4,5)6)14(7,8)9;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11H2,1-10H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t15-;;;/m1.../s1
InChI key
CQCAQRWECWCUBU-JMJDVLNDSA-N
Related Products
Description
- Application: R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can be used:In the asymmetric reduction of amines, ketones and unsaturated acids.[1][2][3]As a hydrogenation catalyst in the preparation of diastereomers of trifluorovaline.[4]As a catalyst in the olefin asymmetric hydrogenation.[5]
- Legal Information: Sold in collaboration with Johnson Matthey for research purposes only.
SAFETY INFORMATION
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 96%
form: solid
mp: 171-177 °C
storage temp.: 2-8°C
SMILES string: [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CP(CP(C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI: 1S/C14H32P2.C8H12.BF4.Rh/c1-12(2,3)15(10)11-16(13(4,5)6)14(7,8)9;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11H2,1-10H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t15-;;;/m1.../s1
InChI key: CQCAQRWECWCUBU-JMJDVLNDSA-N
Quality Level:
100
Assay:
96%
form:
solid
mp:
171-177 °C
storage temp.:
2-8°C
SMILES string:
[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CP(CP(C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI:
1S/C14H32P2.C8H12.BF4.Rh/c1-12(2,3)15(10)11-16(13(4,5)6)14(7,8)9;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11H2,1-10H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t15-;;;/m1.../s1
InChI key:
CQCAQRWECWCUBU-JMJDVLNDSA-N
Quality Level: __
Assay: 97%
form: liquid
mp: __
storage temp.: __
SMILES string: CCOC(=O)C(Br)(Br)Br
InChI: 1S/C4H5Br3O2/c1-2-9-3(8)4(5,6)7/h2H2,1H3
InChI key: ZZUKBDJWZXVOQG-UHFFFAOYSA-N
Quality Level:
__
Assay:
97%
form:
liquid
mp:
__
storage temp.:
__
SMILES string:
CCOC(=O)C(Br)(Br)Br
InChI:
1S/C4H5Br3O2/c1-2-9-3(8)4(5,6)7/h2H2,1H3
InChI key:
ZZUKBDJWZXVOQG-UHFFFAOYSA-N
Quality Level: 100
Assay: 97%
form: powder
mp: 56-58 °C
storage temp.: __
SMILES string: CC1(C)OB(OC1(C)C)c2cnn(Cc3cccs3)c2
InChI: 1S/C14H19BN2O2S/c1-13(2)14(3,4)19-15(18-13)11-8-16-17(9-11)10-12-6-5-7-20-12/h5-9H,10H2,1-4H3
InChI key: ANSBFDYOIUZSNT-UHFFFAOYSA-N
Quality Level:
100
Assay:
97%
form:
powder
mp:
56-58 °C
storage temp.:
__
SMILES string:
CC1(C)OB(OC1(C)C)c2cnn(Cc3cccs3)c2
InChI:
1S/C14H19BN2O2S/c1-13(2)14(3,4)19-15(18-13)11-8-16-17(9-11)10-12-6-5-7-20-12/h5-9H,10H2,1-4H3
InChI key:
ANSBFDYOIUZSNT-UHFFFAOYSA-N
Quality Level: 100
Assay: __
form: powder
mp: __
storage temp.: 2-8°C
SMILES string: O.O.OB(O)c1ccccc1C(O)=O
InChI: 1S/C7H7BO4.2H2O/c9-7(10)5-3-1-2-4-6(5)8(11)12;;/h1-4,11-12H,(H,9,10);2*1H2
InChI key: XHFHPLIGSGHNOD-UHFFFAOYSA-N
Quality Level:
100
Assay:
__
form:
powder
mp:
__
storage temp.:
2-8°C
SMILES string:
O.O.OB(O)c1ccccc1C(O)=O
InChI:
1S/C7H7BO4.2H2O/c9-7(10)5-3-1-2-4-6(5)8(11)12;;/h1-4,11-12H,(H,9,10);2*1H2
InChI key:
XHFHPLIGSGHNOD-UHFFFAOYSA-N