729353

Grubbs Catalyst® M206

Umicore

Manufacturer: Sigma Aldrich

CAS Number: 373640-75-6

Synonym(S): Grubbs Catalyst® M2a SIPR (C933), Dichloro[1,3-bis(2,6-isopropylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II)

Select a Size

Pack Size SKU Availability Price
100 MG 729353-100-MG In Stock ₹ 7,220.00
500 MG 729353-500-MG In Stock ₹ 24,100.00
2 G 729353-2-G In Stock ₹ 66,830.00

729353 - 100 MG

₹ 7,220.00

In Stock

Quantity

1

Base Price: ₹ 7,220.00

GST (18%): ₹ 1,299.60

Total Price: ₹ 8,519.60

form

solid

mp

176-181 °C

storage temp.

2-8°C

SMILES string

C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.CC(C)c4cccc(C(C)C)c4N5CCN(C5[Ru](Cl)(Cl)=Cc6ccccc6)c7c(cccc7C(C)C)C(C)C

InChI

1S/C27H39N2.C18H33P.C7H6.2ClH.Ru/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-14,17-21H,15-16H2,1-8H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2

InChI key

VWYWCKUDPDENIJ-UHFFFAOYSA-L

Other Options

Image Product Name Manufacturer Price Range
BA91985
373640-75-6 | Grubbs Catalyst® M206
A2B Chem --

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Description

  • Application: Bulky NHC ligand results in faster initiation than the Grubbs 2nd Generation Catalyst. Has enabled lower catalyst loadings in some applications.[1][2]
  • Other Notes: Ruthenium-based catalysts for olefin metathesisGrubbs Catalyst® Technology for Olefin Metathesis by Sigma-Aldrich
  • Legal Information: Product of UmicoreProduct LicenseThis product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com

SAFETY INFORMATION

Pictograms

GHS02

Signal Word

Warning

Hazard Statements

H228

Precautionary Statements

P210

Hazard Classifications

Flam. Sol. 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Show Difference

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Sigma Aldrich

729353

Umicore...


form:
solid

mp:
176-181 °C

storage temp.:
2-8°C

SMILES string:
C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.CC(C)c4cccc(C(C)C)c4N5CCN(C5[Ru](Cl)(Cl)=Cc6ccccc6)c7c(cccc7C(C)C)C(C)C

InChI:
1S/C27H39N2.C18H33P.C7H6.2ClH.Ru/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-14,17-21H,15-16H2,1-8H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2

InChI key:
VWYWCKUDPDENIJ-UHFFFAOYSA-L

Img

Supelco

72938

analytical standard, size: 1.0 μm...


form:
aqueous suspensionparticles

mp:
__

storage temp.:
2-8°C

SMILES string:
__

InChI:
__

InChI key:
__

Img

Sigma Aldrich

729388

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form:
solid

mp:
87-91 °C

storage temp.:
__

SMILES string:
Clc1cccc(Br)n1

InChI:
1S/C5H3BrClN/c6-4-2-1-3-5(7)8-4/h1-3H

InChI key:
JWTZSVLLPKTZJP-UHFFFAOYSA-N

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Sigma Aldrich

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form:
crystals

mp:
55-59 °C (lit.)

storage temp.:
__

SMILES string:
CCOC(=O)c1ccc(cc1)[N+]([O-])=O

InChI:
1S/C9H9NO4/c1-2-14-9(11)7-3-5-8(6-4-7)10(12)13/h3-6H,2H2,1H3

InChI key:
PHWSCBWNPZDYRI-UHFFFAOYSA-N