682365

Grubbs Catalyst® M207

Umicore

Manufacturer: Sigma Aldrich

CAS Number: 253688-91-4

Synonym(S): Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](3-methyl-2-butenylidene) (tricyclohexylphosphine)ruthenium(II), Grubbs Catalyst® M2b (C827), Isopentenylidene(1,3-dimesitylimidazolidin-2-ylidene) (tricyclohexylphosphine)ruthenium(II) dichloride, [SIMes]dichloro(3-methyl-2-butenylidene)(tricyclohexylphosphine)Ru(II)

Select a Size

Pack Size SKU Availability Price
100 MG 682365-100-MG In Stock ₹ 1,986.90
500 MG 682365-500-MG In Stock ₹ 9,435.00
2 G 682365-2-G In Stock ₹ 26,684.40

682365 - 100 MG

₹ 1,986.90

In Stock

Quantity

1

Base Price: ₹ 1,986.90

GST (18%): ₹ 357.642

Total Price: ₹ 2,344.542

Quality Level

100

reaction suitability

core: rutheniumreagent type: catalystreaction type: Olefin Metathesis

storage temp.

2-8°C

SMILES string

C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C\C(C)=C/C=[Ru](Cl)(Cl)=C4N(CCN4c5c(C)cc(C)cc5C)c6c(C)cc(C)cc6C

InChI

1S/C21H26N2.C18H33P.C5H8.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-4-5(2)3;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1,4H,2-3H3;2*1H;/q;;;;;+2/p-2

InChI key

LCOFYVWULBZOTA-UHFFFAOYSA-L

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Description

  • General description: Learn more about our metathesis catalysts
  • Application: A general purpose olefin metathesis catalyst similar in reactivity to Grubbs Catalyst® 2nd Generation.
  • Other Notes: Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich
  • Legal Information: Product of UmicoreProduct LicenseThis product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com

SAFETY INFORMATION

Pictograms

GHS02

Signal Word

Warning

Hazard Statements

H228

Precautionary Statements

P210 - P240 - P241 - P280 - P370 + P378

Hazard Classifications

Flam. Sol. 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
100

reaction suitability:
core: rutheniumreagent type: catalystreaction type: Olefin Metathesis

storage temp.:
2-8°C

SMILES string:
C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C\C(C)=C/C=[Ru](Cl)(Cl)=C4N(CCN4c5c(C)cc(C)cc5C)c6c(C)cc(C)cc6C

InChI:
1S/C21H26N2.C18H33P.C5H8.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-4-5(2)3;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1,4H,2-3H3;2*1H;/q;;;;;+2/p-2

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LCOFYVWULBZOTA-UHFFFAOYSA-L

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CC(C)Oc1ccccc1C=[Ru](Cl)(Cl)=C2N(CCN2c3ccccc3C)c4ccccc4C

InChI:
1S/C17H18N2.C10H12O.2ClH.Ru/c1-14-7-3-5-9-16(14)18-11-12-19(13-18)17-10-6-4-8-15(17)2;1-8(2)11-10-7-5-4-6-9(10)3;;;/h3-10H,11-12H2,1-2H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2

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ZDJCARGGZRTYFH-UHFFFAOYSA-L

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SMILES string:
Cc1cc(C)c(N2CCN(C2[Ru](Cl)(Cl)=CCCc3ccccn3)c4c(C)cc(C)cc4C)c(C)c1

InChI:
1S/C21H27N2.C8H9N.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-2-5-8-6-3-4-7-9-8;;;/h9-13H,7-8H2,1-6H3;1,3-4,6-7H,2,5H2;2*1H;/q;;;;+2/p-2

InChI key:
LCRADYBTPYSTNK-UHFFFAOYSA-L

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Quality Level:
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reaction suitability:
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storage temp.:
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SMILES string:
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