[2-(Dicyclohexylphosphino)-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl]gold(I) bis(trifluoromethanesulfonyl)imide
Manufacturer: Sigma Aldrich
CAS Number: 1296269-97-0
Synonym(S): BrettPhos AuNTf2
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 250 MG | 763233-250-MG | In Stock | ₹ 12,980.00 |
| 1 G | 763233-1-G | In Stock | ₹ 45,420.00 |
763233 - 250 MG
In Stock
Quantity
1
Base Price: ₹ 12,980.00
GST (18%): ₹ 2,336.40
Total Price: ₹ 15,316.40
form
solid
Quality Level
100
reaction suitability
core: goldreaction type: Cross Couplingsreagent type: catalyst
mp
192-209 °C (decomposition)
SMILES string
FC(F)(F)S(=O)(=O)N([Au])S(=O)(=O)C(F)(F)F.COc1ccc(OC)c(c1P(C2CCCCC2)C3CCCCC3)-c4c(cc(cc4C(C)C)C(C)C)C(C)C
InChI
1S/C35H53O2P.C2F6NO4S2.Au/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h19-25,27-28H,9-18H2,1-8H3;;/q;-1;+1
InChI key
SMTGSBLIUQSWAP-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences [2-(Dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl]gold(I) bis(trifluoromethanesulfonyl)imide | 1296269-97-0 | MFCD22572681 | 1G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 58,625.71 | |
 | Sigma Aldrich Fine Chemicals Biosciences [2-(Dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl]gold(I) bis(trifluoromethanesulfonyl)imide | 1296269-97-0 | MFCD22572681 | 250MG | Sigma Aldrich Fine Chemicals Biosciences | ₹ 19,809.71 |
Description
- Application: Bulky gold pi-acid catalyst used in oxidative cyclization reactions.
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
Show Difference
form: solid
Quality Level: 100
reaction suitability: core: goldreaction type: Cross Couplingsreagent type: catalyst
mp: 192-209 °C (decomposition)
SMILES string: FC(F)(F)S(=O)(=O)N([Au])S(=O)(=O)C(F)(F)F.COc1ccc(OC)c(c1P(C2CCCCC2)C3CCCCC3)-c4c(cc(cc4C(C)C)C(C)C)C(C)C
InChI: 1S/C35H53O2P.C2F6NO4S2.Au/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h19-25,27-28H,9-18H2,1-8H3;;/q;-1;+1
InChI key: SMTGSBLIUQSWAP-UHFFFAOYSA-N
form: solid
Quality Level: __
reaction suitability: reagent type: ligand
mp: 65-70 °C
SMILES string: C[C@@]12CCC[C@@](C)(CCC1)N2[O]
InChI: 1S/C10H18NO/c1-9-5-3-7-10(2,11(9)12)8-4-6-9/h3-8H2,1-2H3/t9-,10+
InChI key: __
form: solid
Quality Level: 100
reaction suitability: core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystreaction type: Cross Couplings
mp: 193-194 °C (decomposition)
SMILES string: [Na+].Nc1ccccc1-c2ccccc2[Pd]Cl.COc3ccc(c(OC)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6)S([O-])(=O)=O
InChI: 1S/C26H35O5PS.C12H10N.ClH.Na.Pd/c1-30-22-17-18-24(33(27,28)29)26(31-2)25(22)21-15-9-10-16-23(21)32(19-11-5-3-6-12-19)20-13-7-4-8-14-20;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;;/h9-10,15-20H,3-8,11-14H2,1-2H3,(H,27,28,29);1-6,8-9H,13H2;1H;;/q;;;2*+1/p-2
InChI key: MWQYWXJKMDRSJN-UHFFFAOYSA-L
