XPHOS PD G2 ChemBeads
Manufacturer: Sigma Aldrich
CAS Number: 1310584-14-5
Synonym(S): 2nd Generation XPhos Precatalyst, Chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II), X-Phos aminobiphenyl palladium chloride precatalyst, XPhos-Pd-G2
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 927775-1-G | In Stock | ₹ 29,559.30 |
927775 - 1 G
In Stock
Quantity
1
Base Price: ₹ 29,559.30
GST (18%): ₹ 5,320.674
Total Price: ₹ 34,879.974
form
solid
Quality Level
100
composition
~ 5 wt.% loading of catalyst
reaction suitability
reagent type: catalystreaction type: Cross Couplings
SMILES string
Cl[Pd@@]1(C2=C(C3=C(N1)C=CC=C3)C=CC=C2)P(C4CCCCC4)(C5=CC=CC=C5C6=C(C(C)C)C=C(C(C)C)C=C6C(C)C)C7CCCCC7
InChI
1S/C33H49P.C12H10N.ClH.Pd/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;1-6,8-9H,13H2;1H;/q;-1;;+2/p-1
InChI key
HLXMDSGYOJBEBA-UHFFFAOYSA-M
Other Options
Description
- General description: XPhos Pd G2 is a bulky monodentate biaryl ligand. It is a Buchwald′s 2nd generation preformed catalyst. It undergoes rapid reductive elimination to form a reactive, monoligated Pd(0) species.For larger scale uses, product also available in powdered form (741825)
- Application: XPhos Pd G2 was employed as catalyst in the following reactions:Palladium-catalyzed Suzuki-Miyaura coupling reactions of potassium organotrifluoroborates and sulfamates.Suzuki-Miyaura cross-coupling reactions of sensitive aryl and heteroarylboronic acids.Synthesis of potassium Boc-protected secondary aminomethyltrifluoroborates, via Suzuki-Miyaura cross-coupling reaction.2nd Generation Buchwald PrecatalystsWidely used for Suzuki-Miyaura cross-coupling reactionsChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.Learn more about ChemBeads products
- Other Notes: High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass BeadsVersatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput ExperimentationChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
SAFETY INFORMATION
WGK
WGK 3
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form: solid
Quality Level: 100
composition: ~ 5 wt.% loading of catalyst
reaction suitability: reagent type: catalystreaction type: Cross Couplings
SMILES string: Cl[Pd@@]1(C2=C(C3=C(N1)C=CC=C3)C=CC=C2)P(C4CCCCC4)(C5=CC=CC=C5C6=C(C(C)C)C=C(C(C)C)C=C6C(C)C)C7CCCCC7
InChI: 1S/C33H49P.C12H10N.ClH.Pd/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;1-6,8-9H,13H2;1H;/q;-1;;+2/p-1
InChI key: HLXMDSGYOJBEBA-UHFFFAOYSA-M
form: solid
Quality Level: 100
composition: ~ 4 wt.% loading of catalyst
reaction suitability: reagent type: catalystreaction type: Cross Couplings
SMILES string: __
InChI: __
InChI key: __
form: solid
Quality Level: 100
composition: ~ 5 wt.% loading of catalyst
reaction suitability: reagent type: catalystreaction type: Cross Couplings
SMILES string: Cl[Pd]Cl.CN(C)c1ccc(cc1)P(C(C)(C)C)C(C)(C)C.CN(C)c2ccc(cc2)P(C(C)(C)C)C(C)(C)C
InChI: 1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;/q;;;;+2/p-2
InChI key: DWOZNANUEDYIOF-UHFFFAOYSA-L
