928313
tBuBrettPhos Pd G3 ChemBeads
Manufacturer: Sigma Aldrich
CAS Number: 1536473-72-9
Synonym(S): tert-BuBrettPhos-Pd-G3, [(2-Di-tert-butylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 928313-1-G | In Stock | ₹ 28,826.98 |
928313 - 1 G
In Stock
Quantity
1
Base Price: ₹ 28,826.98
GST (18%): ₹ 5,188.856
Total Price: ₹ 34,015.836
form
solid
Quality Level
100
composition
~ 5 wt.% loading of catalyst
reaction suitability
reagent type: catalystreaction type: Cross Couplings
InChI
1S/C31H49O2P.C12H10N.CH4O3S.Pd/c1-19(2)22-17-23(20(3)4)27(24(18-22)21(5)6)28-25(32-13)15-16-26(33-14)29(28)34(30(7,8)9)31(10,11)12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15-21H,1-14H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key
GAQPAUHHECNHNS-UHFFFAOYSA-M
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Description
- General description: tBuBrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.For larger scale uses, product also available in powdered form (745979)
- Application: tBuBrettPhos Pd G3 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.Learn more about ChemBeads products
- Other Notes: High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass BeadsVersatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput ExperimentationChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 1B Inhalation
WGK
WGK 3
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form: solid
Quality Level: 100
composition: ~ 5 wt.% loading of catalyst
reaction suitability: reagent type: catalystreaction type: Cross Couplings
InChI: 1S/C31H49O2P.C12H10N.CH4O3S.Pd/c1-19(2)22-17-23(20(3)4)27(24(18-22)21(5)6)28-25(32-13)15-16-26(33-14)29(28)34(30(7,8)9)31(10,11)12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15-21H,1-14H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key: GAQPAUHHECNHNS-UHFFFAOYSA-M
form:
solid
Quality Level:
100
composition:
~ 5 wt.% loading of catalyst
reaction suitability:
reagent type: catalystreaction type: Cross Couplings
InChI:
1S/C31H49O2P.C12H10N.CH4O3S.Pd/c1-19(2)22-17-23(20(3)4)27(24(18-22)21(5)6)28-25(32-13)15-16-26(33-14)29(28)34(30(7,8)9)31(10,11)12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15-21H,1-14H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key:
GAQPAUHHECNHNS-UHFFFAOYSA-M
form: solid
Quality Level: 100
composition: __
reaction suitability: reagent type: catalystreaction type: Cross Couplings
InChI: __
InChI key: __
form:
solid
Quality Level:
100
composition:
__
reaction suitability:
reagent type: catalystreaction type: Cross Couplings
InChI:
__
InChI key:
__
form: solid
Quality Level: 100
composition: ~ 5 wt.% loading of catalyst
reaction suitability: reagent type: catalystreaction type: Cross Couplings
InChI: 1S/C35H53O2P/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28/h19-25,27-28H,9-18H2,1-8H3
InChI key: WDVGNXKCFBOKDF-UHFFFAOYSA-N
form:
solid
Quality Level:
100
composition:
~ 5 wt.% loading of catalyst
reaction suitability:
reagent type: catalystreaction type: Cross Couplings
InChI:
1S/C35H53O2P/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28/h19-25,27-28H,9-18H2,1-8H3
InChI key:
WDVGNXKCFBOKDF-UHFFFAOYSA-N
form: solid
Quality Level: 100
composition: ~ 4 wt.% loading of catalyst
reaction suitability: reagent type: catalystreaction type: Cross Couplings
InChI: 1S/C39H32OP2/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3
InChI key: CXNIUSPIQKWYAI-UHFFFAOYSA-N
form:
solid
Quality Level:
100
composition:
~ 4 wt.% loading of catalyst
reaction suitability:
reagent type: catalystreaction type: Cross Couplings
InChI:
1S/C39H32OP2/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3
InChI key:
CXNIUSPIQKWYAI-UHFFFAOYSA-N