Home Products Chemistry And Biochemicals Catalysts 763403
SDS
763403

RuPhos Pd G3

98%

Manufacturer: Sigma Aldrich

CAS Number: 1445085-77-7

Synonym(S): (2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, RuPhos-G3-Palladacycle, RuPhos-Pd-G3

Select a Size

Pack Size SKU Availability Price
250 MG 763403-250-MG In Stock ₹ 9,179.70
IND740-1G 763403-IND740-1G In Stock ₹ 12,450.00
1 G 763403-1-G In Stock ₹ 23,150.00
IND740-5G 763403-IND740-5G In Stock ₹ 34,560.00
5 G 763403-5-G In Stock ₹ 1,04,073.60

763403 - 250 MG

₹ 9,179.70

In Stock

Quantity

1

Base Price: ₹ 9,179.70

GST (18%): ₹ 1,652.346

Total Price: ₹ 10,832.046

Quality Level

100

Assay

98%

form

solid

feature

generation 3

reaction suitability

core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystreaction type: Cross Couplings

mp

188-196 °C (decomposition)

functional group

phosphine

SMILES string

CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC(C)Oc3cccc(OC(C)C)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6

InChI

1S/C30H43O2P.C12H10N.CH4O3S.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1

InChI key

AXZLIMCJMPNFFU-UHFFFAOYSA-M

Other Options

Image Product Name Manufacturer Price Range
50-216-5324
eMolecules​ RuPhos Pd G3 | 1445085-77-7 | | 1g
eMolecules​ ₹ 24,620.75
50-269-4225
eMolecules​ Aladdin Scientific Corporation (2-Dicyclohexylphosphino-2?6?-diisopropoxy-11?-biphenyl)[2-(2?-amino-11?-biphenyl)]palladium(II) methanesulfonate 25g 845266592 M396600 1445085-77-7 [null] 838.390 C43H58NO5PPdS
eMolecules​ ₹ 3,83,591.15
50-201-6646
Strem, An Ascensus Company CAS# 1445085-77-7. 1g. Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RuPhos Palladacycle Gen. 3]. MFCD22572684
Strem, An Ascensus Company ₹ 21,663.79
50-173-8590
Sigma Aldrich Fine Chemicals Biosciences RuPhos Pd G3 98% | 1445085-77-7 | MFCD22572684 | 5G
Sigma Aldrich Fine Chemicals Biosciences ₹ 1,03,989.62
50-1738-588
Sigma Aldrich Fine Chemicals Biosciences RuPhos Pd G3 | 1445085-77-7 | MFCD22572684 | 1G
Sigma Aldrich Fine Chemicals Biosciences ₹ 26,831.62
NC2154937
eMolecules​ Strem Chemicals | Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) | 5g | 321339304 | 46-0314 | 98.000 | 1445085-77-7 | | 836.380 | C43H56NO5PPdS
eMolecules​ ₹ 1,13,949.66
50-201-6647
Strem, An Ascensus Company CAS# 1445085-77-7. 250mg. Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RuPhos Palladacycle Gen. 3]. MFCD22572684
Strem, An Ascensus Company ₹ 6,776.35
50-201-6648
Strem, An Ascensus Company CAS# 1445085-77-7. 5g. Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RuPhos Palladacycle Gen. 3]. MFCD22572684
Strem, An Ascensus Company ₹ 92,202.88
928283
RuPhos Pd G3 ChemBeads
Sigma Aldrich ₹ 27,679.53
AR001KCR
[2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexylphosphine-κP](methanesulfonato-κO)palladium
Aaron Chemicals LLC ₹ 342.24 - ₹ 1,22,265.24

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Description

  • General description: RuPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
  • Application: RuPhos Pd G3 can be used as a pre-catalyst in the following protocols:Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles.[1]Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers.[2]Suzuki-Miyaura-cross-coupling of aminothiophenes.[3]For small scale and high throughput uses, product is also available as ChemBeads (928283)

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315 - H319 - H335 - H412

Precautionary Statements

P273 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Compare Similar Items

Show Difference

Img

Sigma Aldrich

763403

98%...

Quality Level:
100
Assay:
98%
form:
solid
feature:
generation 3
reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystreaction type: Cross Couplings
mp:
188-196 °C (decomposition)
functional group:
phosphine
SMILES string:
CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC(C)Oc3cccc(OC(C)C)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6
InChI:
1S/C30H43O2P.C12H10N.CH4O3S.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key:
AXZLIMCJMPNFFU-UHFFFAOYSA-M

Img

Sigma Aldrich

763543

98% (HPLC)...

Quality Level:
100
Assay:
98% (HPLC)
form:
liquid
feature:
__
reaction suitability:
__
mp:
__
functional group:
__
SMILES string:
CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)OCC(C)(COC(=O)C(C)(C)SC(=S)SCCCCCCCCCCCC)COC(=O)C(C)(C)SC(=S)SCCCCCCCCCCCC
InChI:
1S/C56H102O6S9/c1-11-14-17-20-23-26-29-32-35-38-41-66-50(63)69-53(4,5)47(57)60-44-56(10,45-61-48(58)54(6,7)70-51(64)67-42-39-36-33-30-27-24-21-18-15-12-2)46-62-49(59)55(8,9)71-52(65)68-43-40-37-34-31-28-25-22-19-16-13-3/h11-46H2,1-10H3
InChI key:
HYZIWJXWRIAPNA-UHFFFAOYSA-N

Img

Tocris Bioscience™

763550U

--

Quality Level:
__
Assay:
__
form:
__
feature:
__
reaction suitability:
__
mp:
__
functional group:
__
SMILES string:
__
InChI:
__
InChI key:
__

Img

Sigma Aldrich

763551

97% (HPLC)...

Quality Level:
100
Assay:
97% (HPLC)
form:
solid
feature:
__
reaction suitability:
__
mp:
30-34 °C
functional group:
__
SMILES string:
CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)OCC(COC(=O)C(C)(C)SC(=S)SCCCCCCCCCCCC)(COC(=O)C(C)(C)SC(=S)SCCCCCCCCCCCC)COC(=O)C(C)(C)SC(=S)SCCCCCCCCCCCC
InChI:
1S/C73H132O8S12/c1-13-17-21-25-29-33-37-41-45-49-53-86-65(82)90-69(5,6)61(74)78-57-73(58-79-62(75)70(7,8)91-66(83)87-54-50-46-42-38-34-30-26-22-18-14-2,59-80-63(76)71(9,10)92-67(84)88-55-51-47-43-39-35-31-27-23-19-15-3)60-81-64(77)72(11,12)93-68(85)89-56-52-48-44-40-36-32-28-24-20-16-4/h13-60H2,1-12H3
InChI key:
ONXYMIIQXBMPMD-UHFFFAOYSA-N