791016

RockPhos

97%

Manufacturer: Sigma Aldrich

CAS Number: 1262046-34-3

Synonym(S): 2-Di(tert-butyl)phosphino-2′,4′,6′-triisopropyl-3-methoxy-6-methylbiphenyl, Di-tert-butyl(2′,4′,6′-triisopropyl-3-methoxy-6-methyl-[1,1′-biphenyl]-2-yl)phosphine

Select a Size

Pack Size SKU Availability Price
500 MG 791016-500-MG In Stock ₹ 56,723.00
2 G 791016-2-G In Stock ₹ 1,27,540.15

791016 - 500 MG

₹ 56,723.00

In Stock

Quantity

1

Base Price: ₹ 56,723.00

GST (18%): ₹ 10,210.14

Total Price: ₹ 66,933.14

Quality Level

100

Assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligandreaction type: Cross Couplings

mp

121-131 °C

functional group

phosphine

storage temp.

15-25°C

SMILES string

CC1=C(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)C(P(C(C)(C)C)C(C)(C)C)=C(OC)C=C1

InChI

1S/C31H49OP/c1-19(2)23-17-24(20(3)4)28(25(18-23)21(5)6)27-22(7)15-16-26(32-14)29(27)33(30(8,9)10)31(11,12)13/h15-21H,1-14H3

InChI key

CVLLAKCGAFNZHJ-UHFFFAOYSA-N

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Description

  • Application: RockPhos is a biphenyl-based phosphine ligand used with Pd(0) catalyst for carbon-carbon and carbon-heteroatom bond formation reactions.[1][2]It can also be employed in the: 2-fluroethoxylation of bromo-chalcones in the presence of palladium catalyst.[2]Conversion of aryl chlorides into aryl methoxides using RockPhos Pd G3 as a catalyst.[3]

SAFETY INFORMATION

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Show Difference

Img

Sigma Aldrich

791016

97%...


Quality Level:
100

Assay:
97%

form:
solid

reaction suitability:
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligandreaction type: Cross Couplings

mp:
121-131 °C

functional group:
phosphine

storage temp.:
15-25°C

SMILES string:
CC1=C(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)C(P(C(C)(C)C)C(C)(C)C)=C(OC)C=C1

InChI:
1S/C31H49OP/c1-19(2)23-17-24(20(3)4)28(25(18-23)21(5)6)27-22(7)15-16-26(32-14)29(27)33(30(8,9)10)31(11,12)13/h15-21H,1-14H3

InChI key:
CVLLAKCGAFNZHJ-UHFFFAOYSA-N

Img

Sigma Aldrich

791056P

--


Quality Level:
__

Assay:
>99% (TLC)

form:
powder

reaction suitability:
__

mp:
__

functional group:
__

storage temp.:
−20°C

SMILES string:
__

InChI:
__

InChI key:
__

Img

Supelco

79109

analytical standard...


Quality Level:
100

Assay:
≥99.8% (GC)

form:
__

reaction suitability:
__

mp:
__

functional group:
__

storage temp.:
__

SMILES string:
__

InChI:
__

InChI key:
__

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Sigma Aldrich

791105

95% (H-NMR)...


Quality Level:
100

Assay:
95% (H-NMR)

form:
solid

reaction suitability:
reaction type: C-C Bond Formationreagent type: catalystreaction type: C-H Activationreagent type: diversification reagent

mp:
190-195 °C

functional group:
__

storage temp.:
2-8°C

SMILES string:
ClCS(O[Zn]OS(CCl)=O)=O

InChI:
1S/2CH3ClO2S.Zn/c2*2-1-5(3)4;/h2*1H2,(H,3,4);/q;;+2/p-2

InChI key:
HEKATMPPXNXYJU-UHFFFAOYSA-L