AdBrettPhos
95%
Manufacturer: Sigma Aldrich
CAS Number: 1160861-59-5
Synonym(S): Di-Ad-BrettPhos
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 768154-100-MG | In Stock | ₹ 12,697.73 |
| 500 MG | 768154-500-MG | In Stock | ₹ 60,273.60 |
| 1 G | 768154-1-G | In Stock | ₹ 72,906.38 |
768154 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 12,697.73
GST (18%): ₹ 2,285.591
Total Price: ₹ 14,983.321
Quality Level
100
Assay
95%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand
mp
231-235 °C
functional group
phosphine
SMILES string
COc1ccc(OC)c(c1P(C23CC4CC(CC(C4)C2)C3)C56CC7CC(CC(C7)C5)C6)-c8c(cc(cc8C(C)C)C(C)C)C(C)C
InChI
1S/C43H61O2P/c1-25(2)34-17-35(26(3)4)39(36(18-34)27(5)6)40-37(44-7)9-10-38(45-8)41(40)46(42-19-28-11-29(20-42)13-30(12-28)21-42)43-22-31-14-32(23-43)16-33(15-31)24-43/h9-10,17-18,25-33H,11-16,19-24H2,1-8H3
InChI key
NMGHOZQCYNKWBG-UHFFFAOYSA-N
Other Options
Related Products
Description
- General description: AdBrettPhos is a phosphine-based ligand used in the direct monoarylation of ammonia and suppresses diarylation. In addition, it is a good ligand for five-membered heteroarene couplings and is employed in the preparation of phosphine-ligated palladium complexes to facilitate C-N coupling reactions. [1]
- Application: AdBrettPhos can be used as an effective ligand for synthesizing [(L·Pd)n ·(1,5-cyclooctadiene)] pre-catalyst that can be used for the Pd-catalyzed fluorination of aryl triflates.[2]AdBrettPhos has been used in the Palladium-Catalyzed C-O Cross-Coupling of Primary Alcohols.[3]
SAFETY INFORMATION
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Quality Level: 100
Assay: 95%
form: solid
reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand
mp: 231-235 °C
functional group: phosphine
SMILES string: COc1ccc(OC)c(c1P(C23CC4CC(CC(C4)C2)C3)C56CC7CC(CC(C7)C5)C6)-c8c(cc(cc8C(C)C)C(C)C)C(C)C
InChI: 1S/C43H61O2P/c1-25(2)34-17-35(26(3)4)39(36(18-34)27(5)6)40-37(44-7)9-10-38(45-8)41(40)46(42-19-28-11-29(20-42)13-30(12-28)21-42)43-22-31-14-32(23-43)16-33(15-31)24-43/h9-10,17-18,25-33H,11-16,19-24H2,1-8H3
InChI key: NMGHOZQCYNKWBG-UHFFFAOYSA-N
Quality Level: 100
Assay: 97%
form: solid
reaction suitability: core: goldreagent type: catalyst
mp: 236-299 °C (decomposition)
functional group: __
SMILES string: Cl[Au].CN(C)c1ccccc1P(C23CC4CC(CC(C4)C2)C3)C56CC7CC(CC(C7)C5)C6
InChI: 1S/C28H40NP.Au.ClH/c1-29(2)25-5-3-4-6-26(25)30(27-13-19-7-20(14-27)9-21(8-19)15-27)28-16-22-10-23(17-28)12-24(11-22)18-28;;/h3-6,19-24H,7-18H2,1-2H3;;1H/q;+1;/p-1
InChI key: JCSJEPVSKVFFRE-UHFFFAOYSA-M
Quality Level: 100
Assay: __
form: liquid
reaction suitability: __
mp: __
functional group: __
SMILES string: CC(C)(\N=N\C(C)(C)C#N)C#N
InChI: 1S/C8H12N4/c1-7(2,5-9)11-12-8(3,4)6-10/h1-4H3/b12-11+
InChI key: OZAIFHULBGXAKX-VAWYXSNFSA-N
