794139
(η5 -Cyclopentadienyl)[N,N-dimethyl-Ν′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate
Manufacturer: Sigma Aldrich
CAS Number: 1603164-23-3
Synonym(S): Herzon Reductive Hydration Catalyst
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 794139-100-MG | In Stock | ₹ 9,790.20 |
794139 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 9,790.20
GST (18%): ₹ 1,762.236
Total Price: ₹ 11,552.436
form
powder
Quality Level
100
reaction suitability
core: rutheniumreagent type: catalyst
mp
>180 °C
SMILES string
CN(C)CCC/N=C/C1=NC=CC=C1.F[P-](F)(F)(F)(F)F.[C]2[C][C][C][C]2.[Ru+]
InChI
1S/C11H17N3.C5H5.F6P.Ru/c1-14(2)9-5-7-12-10-11-6-3-4-8-13-11;1-2-4-5-3-1;1-7(2,3,4,5)6;/h3-4,6,8,10H,5,7,9H2,1-2H3;1-5H;;/q;;-1;+1/b12-10+;;;
InChI key
KUSUXOOKLDLSSI-AKMNYRKMSA-N
Related Products
Description
- General description: (η5 -Cyclopentadienyl)[N,N-dimethyl-N′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate is also referred to as Herzon reductive hydration catalyst. Herzon reductive hydration catalyst is a half-sandwich ruthenium complex. It is a tridentate nitrogen-based ligand containing a hemilabile 3-(dimethylamino)propyl group. It participates in the conversion of terminal alkynes to linear alcohols.[1]
- Application: Catalyst mediates the transformation of alkynes to alcohols through an anti-Markovnikov addition. This reaction occurs at room temperature with the use of formic acid to assist in the reduction of the intermediate aldehyde to the corresponding alcohol.
- Other Notes: A Highly Active and Air-Stable Ruthenium Complex for the Ambient Temperature Anti-Markovnikov Reductive Hydration of Terminal Alkynes
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
Show Difference
form: powder
Quality Level: 100
reaction suitability: core: rutheniumreagent type: catalyst
mp: >180 °C
SMILES string: CN(C)CCC/N=C/C1=NC=CC=C1.F[P-](F)(F)(F)(F)F.[C]2[C][C][C][C]2.[Ru+]
InChI: 1S/C11H17N3.C5H5.F6P.Ru/c1-14(2)9-5-7-12-10-11-6-3-4-8-13-11;1-2-4-5-3-1;1-7(2,3,4,5)6;/h3-4,6,8,10H,5,7,9H2,1-2H3;1-5H;;/q;;-1;+1/b12-10+;;;
InChI key: KUSUXOOKLDLSSI-AKMNYRKMSA-N
form:
powder
Quality Level:
100
reaction suitability:
core: rutheniumreagent type: catalyst
mp:
>180 °C
SMILES string:
CN(C)CCC/N=C/C1=NC=CC=C1.F[P-](F)(F)(F)(F)F.[C]2[C][C][C][C]2.[Ru+]
InChI:
1S/C11H17N3.C5H5.F6P.Ru/c1-14(2)9-5-7-12-10-11-6-3-4-8-13-11;1-2-4-5-3-1;1-7(2,3,4,5)6;/h3-4,6,8,10H,5,7,9H2,1-2H3;1-5H;;/q;;-1;+1/b12-10+;;;
InChI key:
KUSUXOOKLDLSSI-AKMNYRKMSA-N
form: solution
Quality Level: 100
reaction suitability: __
mp: __
SMILES string: CN(C)P(=NC(C)(C)C)(N=P(N(C)C)(N(C)C)N(C)C)N(C)C
InChI: 1S/C14H39N7P2/c1-14(2,3)15-22(17(4)5,18(6)7)16-23(19(8)9,20(10)11)21(12)13/h1-13H3
InChI key: CJTQESMNKMUZAO-UHFFFAOYSA-N
form:
solution
Quality Level:
100
reaction suitability:
__
mp:
__
SMILES string:
CN(C)P(=NC(C)(C)C)(N=P(N(C)C)(N(C)C)N(C)C)N(C)C
InChI:
1S/C14H39N7P2/c1-14(2,3)15-22(17(4)5,18(6)7)16-23(19(8)9,20(10)11)21(12)13/h1-13H3
InChI key:
CJTQESMNKMUZAO-UHFFFAOYSA-N
form: solution
Quality Level: 100
reaction suitability: __
mp: __
SMILES string: CN(C)P(=NC(C)(C)C)(N=P(N(C)C)(N(C)C)N(C)C)N(C)C
InChI: 1S/C14H39N7P2/c1-14(2,3)15-22(17(4)5,18(6)7)16-23(19(8)9,20(10)11)21(12)13/h1-13H3
InChI key: CJTQESMNKMUZAO-UHFFFAOYSA-N
form:
solution
Quality Level:
100
reaction suitability:
__
mp:
__
SMILES string:
CN(C)P(=NC(C)(C)C)(N=P(N(C)C)(N(C)C)N(C)C)N(C)C
InChI:
1S/C14H39N7P2/c1-14(2,3)15-22(17(4)5,18(6)7)16-23(19(8)9,20(10)11)21(12)13/h1-13H3
InChI key:
CJTQESMNKMUZAO-UHFFFAOYSA-N
form: liquid
Quality Level: 100
reaction suitability: __
mp: __
SMILES string: CCN=P(N=P(N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C
InChI: 1S/C12H35N7P2/c1-12-13-20(15(2)3,16(4)5)14-21(17(6)7,18(8)9)19(10)11/h12H2,1-11H3
InChI key: CFUKEHPEQCSIOM-UHFFFAOYSA-N
form:
liquid
Quality Level:
100
reaction suitability:
__
mp:
__
SMILES string:
CCN=P(N=P(N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C
InChI:
1S/C12H35N7P2/c1-12-13-20(15(2)3,16(4)5)14-21(17(6)7,18(8)9)19(10)11/h12H2,1-11H3
InChI key:
CFUKEHPEQCSIOM-UHFFFAOYSA-N