794279
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
Manufacturer: Sigma Aldrich
CAS Number: 27057-09-6
Synonym(S): Buchwald Nickel Cross-Coupling Catalyst Precursor, [Bis(triphenylphosphine)](o-tolyl)chloronickel
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 250 MG | 794279-250-MG | In Stock | ₹ 14,505.50 |
| 1 G | 794279-1-G | In Stock | ₹ 38,060.70 |
794279 - 250 MG
In Stock
Quantity
1
Base Price: ₹ 14,505.50
GST (18%): ₹ 2,610.99
Total Price: ₹ 17,116.49
form
solid
Quality Level
100
reaction suitability
core: nickelreagent type: catalyst
mp
195-200 °C
storage temp.
2-8°C
SMILES string
Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
InChI
1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1
InChI key
QVGJKVLYWZGANE-UHFFFAOYSA-M
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) | 27057-09-6 | 1G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 38,675.69 | |
 | Sigma Aldrich Fine Chemicals Biosciences Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) | 27057-09-6 | 250MG | Sigma Aldrich Fine Chemicals Biosciences | ₹ 14,673.54 | |
 | 27057-09-6 | Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II) | A2B Chem | ₹ 1,454.52 - ₹ 5,732.52 |
Related Products
Description
- Application: Product is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers.
- Other Notes: Development of an Air-Stable Nickel Precatalyst for the Amination of Aryl Chlorides, Sulfamates, Mesylates, and Triflates
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 1B - Skin Sens. 1
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
Show Difference
form: solid
Quality Level: 100
reaction suitability: core: nickelreagent type: catalyst
mp: 195-200 °C
storage temp.: 2-8°C
SMILES string: Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
InChI: 1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1
InChI key: QVGJKVLYWZGANE-UHFFFAOYSA-M
form:
solid
Quality Level:
100
reaction suitability:
core: nickelreagent type: catalyst
mp:
195-200 °C
storage temp.:
2-8°C
SMILES string:
Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
InChI:
1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1
InChI key:
QVGJKVLYWZGANE-UHFFFAOYSA-M
form: solid
Quality Level: 100
reaction suitability: __
mp: 48 °C
storage temp.: 2-8°C
SMILES string: CC(C(C)(C)O1)(C)OB1CB2OC(C)(C)C(C)(C)O2
InChI: 1S/C13H26B2O4/c1-10(2)11(3,4)17-14(16-10)9-15-18-12(5,6)13(7,8)19-15/h9H2,1-8H3
InChI key: MQYZGGWWHUGYDR-UHFFFAOYSA-N
form:
solid
Quality Level:
100
reaction suitability:
__
mp:
48 °C
storage temp.:
2-8°C
SMILES string:
CC(C(C)(C)O1)(C)OB1CB2OC(C)(C)C(C)(C)O2
InChI:
1S/C13H26B2O4/c1-10(2)11(3,4)17-14(16-10)9-15-18-12(5,6)13(7,8)19-15/h9H2,1-8H3
InChI key:
MQYZGGWWHUGYDR-UHFFFAOYSA-N
form: liquid
Quality Level: 100
reaction suitability: __
mp: −24 °C (lit.)
storage temp.: 2-8°C
SMILES string: CC(C)(C)N=P(N1CCCC1)(N2CCCC2)N3CCCC3
InChI: 1S/C16H33N4P/c1-16(2,3)17-21(18-10-4-5-11-18,19-12-6-7-13-19)20-14-8-9-15-20/h4-15H2,1-3H3
InChI key: __
form:
liquid
Quality Level:
100
reaction suitability:
__
mp:
−24 °C (lit.)
storage temp.:
2-8°C
SMILES string:
CC(C)(C)N=P(N1CCCC1)(N2CCCC2)N3CCCC3
InChI:
1S/C16H33N4P/c1-16(2,3)17-21(18-10-4-5-11-18,19-12-6-7-13-19)20-14-8-9-15-20/h4-15H2,1-3H3
InChI key:
__
form: liquid
Quality Level: 100
reaction suitability: __
mp: −24 °C (lit.)
storage temp.: 2-8°C
SMILES string: CC(C)(C)N=P(N1CCCC1)(N2CCCC2)N3CCCC3
InChI: 1S/C16H33N4P/c1-16(2,3)17-21(18-10-4-5-11-18,19-12-6-7-13-19)20-14-8-9-15-20/h4-15H2,1-3H3
InChI key: __
form:
liquid
Quality Level:
100
reaction suitability:
__
mp:
−24 °C (lit.)
storage temp.:
2-8°C
SMILES string:
CC(C)(C)N=P(N1CCCC1)(N2CCCC2)N3CCCC3
InChI:
1S/C16H33N4P/c1-16(2,3)17-21(18-10-4-5-11-18,19-12-6-7-13-19)20-14-8-9-15-20/h4-15H2,1-3H3
InChI key:
__