798436
Endo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine
Manufacturer: Sigma Aldrich
Synonym(S): (1S,4S,5S)-5-(naphthalen-1-yl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 798436-100-MG | In Stock | ₹ 8,356.90 |
798436 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 8,356.90
GST (18%): ₹ 1,504.242
Total Price: ₹ 9,861.142
form
powder
Quality Level
100
storage condition
under inert gas
storage temp.
2-8°C
SMILES string
O=S(N1C[C@H]2[P@@](C3=CC=CC4=C3C=CC=C4)C[C@@H]1C2)(C5=CC=C(C)C=C5)=O
InChI
1S/C22H22NO2PS/c1-16-9-11-20(12-10-16)27(24,25)23-14-19-13-18(23)15-26(19)22-8-4-6-17-5-2-3-7-21(17)22/h2-12,18-19H,13-15H2,1H3
InChI key
RGHUOMJULXTHPX-UHFFFAOYSA-N
Related Products
Description
- Application: The bicyclic, chiral phosphine was developed by the Kwon Research Group. Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.
- Other Notes: Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-PyrrolinesTechnology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from HydroxyprolineAldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
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form: powder
Quality Level: 100
storage condition: under inert gas
storage temp.: 2-8°C
SMILES string: O=S(N1C[C@H]2[P@@](C3=CC=CC4=C3C=CC=C4)C[C@@H]1C2)(C5=CC=C(C)C=C5)=O
InChI: 1S/C22H22NO2PS/c1-16-9-11-20(12-10-16)27(24,25)23-14-19-13-18(23)15-26(19)22-8-4-6-17-5-2-3-7-21(17)22/h2-12,18-19H,13-15H2,1H3
InChI key: RGHUOMJULXTHPX-UHFFFAOYSA-N
form:
powder
Quality Level:
100
storage condition:
under inert gas
storage temp.:
2-8°C
SMILES string:
O=S(N1C[C@H]2[P@@](C3=CC=CC4=C3C=CC=C4)C[C@@H]1C2)(C5=CC=C(C)C=C5)=O
InChI:
1S/C22H22NO2PS/c1-16-9-11-20(12-10-16)27(24,25)23-14-19-13-18(23)15-26(19)22-8-4-6-17-5-2-3-7-21(17)22/h2-12,18-19H,13-15H2,1H3
InChI key:
RGHUOMJULXTHPX-UHFFFAOYSA-N
form: powder
Quality Level: 100
storage condition: __
storage temp.: 2-8°C
SMILES string: O=S(N1C[C@H]2[P@@](C3=CC=C(OC)C=C3)C[C@@H]1C2)(C4=CC=C(C)C=C4)=O
InChI: 1S/C19H22NO3PS/c1-14-3-9-19(10-4-14)25(21,22)20-12-18-11-15(20)13-24(18)17-7-5-16(23-2)6-8-17/h3-10,15,18H,11-13H2,1-2H3
InChI key: RMFZMNUGIFSNIE-UHFFFAOYSA-N
form:
powder
Quality Level:
100
storage condition:
__
storage temp.:
2-8°C
SMILES string:
O=S(N1C[C@H]2[P@@](C3=CC=C(OC)C=C3)C[C@@H]1C2)(C4=CC=C(C)C=C4)=O
InChI:
1S/C19H22NO3PS/c1-14-3-9-19(10-4-14)25(21,22)20-12-18-11-15(20)13-24(18)17-7-5-16(23-2)6-8-17/h3-10,15,18H,11-13H2,1-2H3
InChI key:
RMFZMNUGIFSNIE-UHFFFAOYSA-N
form: crystals
Quality Level: 100
storage condition: __
storage temp.: 2-8°C
SMILES string: OC[C@H]1O[C@@H](OC2=C(Oc3cc(O)cc(O)c3C2=O)c4ccc(O)cc4)[C@H](O)[C@@H](O)[C@@H]1O
InChI: 1S/C21H20O11/c22-7-13-15(26)17(28)18(29)21(31-13)32-20-16(27)14-11(25)5-10(24)6-12(14)30-19(20)8-1-3-9(23)4-2-8/h1-6,13,15,17-18,21-26,28-29H,7H2/t13-,15-,17+,18-,21+/m1/s1
InChI key: JPUKWEQWGBDDQB-QSOFNFLRSA-N
form:
crystals
Quality Level:
100
storage condition:
__
storage temp.:
2-8°C
SMILES string:
OC[C@H]1O[C@@H](OC2=C(Oc3cc(O)cc(O)c3C2=O)c4ccc(O)cc4)[C@H](O)[C@@H](O)[C@@H]1O
InChI:
1S/C21H20O11/c22-7-13-15(26)17(28)18(29)21(31-13)32-20-16(27)14-11(25)5-10(24)6-12(14)30-19(20)8-1-3-9(23)4-2-8/h1-6,13,15,17-18,21-26,28-29H,7H2/t13-,15-,17+,18-,21+/m1/s1
InChI key:
JPUKWEQWGBDDQB-QSOFNFLRSA-N
form: powder or crystals (anhydrous)
Quality Level: 100
storage condition: __
storage temp.: __
SMILES string: __
InChI: __
InChI key: __
form:
powder or crystals (anhydrous)
Quality Level:
100
storage condition:
__
storage temp.:
__
SMILES string:
__
InChI:
__
InChI key:
__