798339
Exo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine
Manufacturer: Sigma Aldrich
Synonym(S): (1S,4S,5R)-5-(naphthalen-1-yl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 798339-100-MG | In Stock | ₹ 9,547.65 |
798339 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 9,547.65
GST (18%): ₹ 1,718.577
Total Price: ₹ 11,266.227
form
powder
Quality Level
100
storage condition
under inert gas
storage temp.
2-8°C
SMILES string
O=S(N1C[C@@]2([H])[P@](C3=CC=CC4=C3C=CC=C4)C[C@]1([H])C2)(C5=CC=C(C)C=C5)=O
InChI
1S/C22H22NO2PS/c1-16-9-11-20(12-10-16)27(24,25)23-14-19-13-18(23)15-26(19)22-8-4-6-17-5-2-3-7-21(17)22/h2-12,18-19H,13-15H2,1H3/t18-,19-,26?/m0/s1
InChI key
RGHUOMJULXTHPX-OCOBAGFRSA-N
Related Products
Description
- Application: The bicyclic, chiral phosphine was developed by the Kwon Research Group.Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.
- Other Notes: Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-PyrrolinesTechnology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from HydroxyprolineAldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
Show Difference
form: powder
Quality Level: 100
storage condition: under inert gas
storage temp.: 2-8°C
SMILES string: O=S(N1C[C@@]2([H])[P@](C3=CC=CC4=C3C=CC=C4)C[C@]1([H])C2)(C5=CC=C(C)C=C5)=O
InChI: 1S/C22H22NO2PS/c1-16-9-11-20(12-10-16)27(24,25)23-14-19-13-18(23)15-26(19)22-8-4-6-17-5-2-3-7-21(17)22/h2-12,18-19H,13-15H2,1H3/t18-,19-,26?/m0/s1
InChI key: RGHUOMJULXTHPX-OCOBAGFRSA-N
form:
powder
Quality Level:
100
storage condition:
under inert gas
storage temp.:
2-8°C
SMILES string:
O=S(N1C[C@@]2([H])[P@](C3=CC=CC4=C3C=CC=C4)C[C@]1([H])C2)(C5=CC=C(C)C=C5)=O
InChI:
1S/C22H22NO2PS/c1-16-9-11-20(12-10-16)27(24,25)23-14-19-13-18(23)15-26(19)22-8-4-6-17-5-2-3-7-21(17)22/h2-12,18-19H,13-15H2,1H3/t18-,19-,26?/m0/s1
InChI key:
RGHUOMJULXTHPX-OCOBAGFRSA-N
form: powder
Quality Level: 100
storage condition: under inert gas
storage temp.: 2-8°C
SMILES string: O=S(N1C[C@@]2([H])[P@@](C3=CC=CC=C3)C[C@]1([H])C2)(C4=CC=C(C)C=C4)=O
InChI: 1S/C18H20NO2PS/c1-14-7-9-18(10-8-14)23(20,21)19-12-17-11-15(19)13-22(17)16-5-3-2-4-6-16/h2-10,15,17H,11-13H2,1H3/t15-,17-,22?/m0/s1
InChI key: BWXYDSDVFPJTFY-TWMUNHRGSA-N
form:
powder
Quality Level:
100
storage condition:
under inert gas
storage temp.:
2-8°C
SMILES string:
O=S(N1C[C@@]2([H])[P@@](C3=CC=CC=C3)C[C@]1([H])C2)(C4=CC=C(C)C=C4)=O
InChI:
1S/C18H20NO2PS/c1-14-7-9-18(10-8-14)23(20,21)19-12-17-11-15(19)13-22(17)16-5-3-2-4-6-16/h2-10,15,17H,11-13H2,1H3/t15-,17-,22?/m0/s1
InChI key:
BWXYDSDVFPJTFY-TWMUNHRGSA-N
form: powder
Quality Level: 100
storage condition: under inert gas
storage temp.: 2-8°C
SMILES string: O=S(N1C[C@H]2[P@@](C3=CC=CC4=C3C=CC=C4)C[C@@H]1C2)(C5=CC=C(C)C=C5)=O
InChI: 1S/C22H22NO2PS/c1-16-9-11-20(12-10-16)27(24,25)23-14-19-13-18(23)15-26(19)22-8-4-6-17-5-2-3-7-21(17)22/h2-12,18-19H,13-15H2,1H3
InChI key: RGHUOMJULXTHPX-UHFFFAOYSA-N
form:
powder
Quality Level:
100
storage condition:
under inert gas
storage temp.:
2-8°C
SMILES string:
O=S(N1C[C@H]2[P@@](C3=CC=CC4=C3C=CC=C4)C[C@@H]1C2)(C5=CC=C(C)C=C5)=O
InChI:
1S/C22H22NO2PS/c1-16-9-11-20(12-10-16)27(24,25)23-14-19-13-18(23)15-26(19)22-8-4-6-17-5-2-3-7-21(17)22/h2-12,18-19H,13-15H2,1H3
InChI key:
RGHUOMJULXTHPX-UHFFFAOYSA-N
form: powder
Quality Level: 100
storage condition: __
storage temp.: 2-8°C
SMILES string: O=S(N1C[C@H]2[P@@](C3=CC=C(OC)C=C3)C[C@@H]1C2)(C4=CC=C(C)C=C4)=O
InChI: 1S/C19H22NO3PS/c1-14-3-9-19(10-4-14)25(21,22)20-12-18-11-15(20)13-24(18)17-7-5-16(23-2)6-8-17/h3-10,15,18H,11-13H2,1-2H3
InChI key: RMFZMNUGIFSNIE-UHFFFAOYSA-N
form:
powder
Quality Level:
100
storage condition:
__
storage temp.:
2-8°C
SMILES string:
O=S(N1C[C@H]2[P@@](C3=CC=C(OC)C=C3)C[C@@H]1C2)(C4=CC=C(C)C=C4)=O
InChI:
1S/C19H22NO3PS/c1-14-3-9-19(10-4-14)25(21,22)20-12-18-11-15(20)13-24(18)17-7-5-16(23-2)6-8-17/h3-10,15,18H,11-13H2,1-2H3
InChI key:
RMFZMNUGIFSNIE-UHFFFAOYSA-N