804215
[Ir{dFCF3ppy}2(bpy)]PF6
Manufacturer: Sigma Aldrich
CAS Number: 1092775-62-6
Synonym(S): [Ir[dF(CF3)2ppy]2(bpy)]PF6
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 50 MG | 804215-50-MG | In Stock | ₹ 9,357.30 |
804215 - 50 MG
In Stock
Quantity
1
Base Price: ₹ 9,357.30
GST (18%): ₹ 1,684.314
Total Price: ₹ 11,041.614
form
powder
Quality Level
100
reaction suitability
core: iridiumreagent type: catalystreaction type: Photocatalysis
photocatalyst activation
450 nm
SMILES string
FP(F)(F)(F)F.FC1=CC(F)=C(C2=[N]3C=C(C(F)(F)F)C=C2)C([Ir+]345([N]6=C(C7=CC=CC=[N]75)C=CC=C6)[N]8=C(C9=C(F)C=C(F)C=C94)C=CC(C(F)(F)F)=C8)=C1.[F-]
InChI
1S/2C12H5F5N.C10H8N2.F5P.FH.Ir/c2*13-8-2-3-9(10(14)5-8)11-4-1-7(6-18-11)12(15,16)17;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-6(2,3,4)5;;/h2*1-2,4-6H;1-8H;;1H;/q;;;;;+1/p-1
InChI key
DZIQZTFRUCLPRL-UHFFFAOYSA-M
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Ambeed | 1092775-62-6 | | 1G | Ambeed | ₹ 31,682.87 | |
| | eMolecules [IR{DFCF3PPY2(BPY)]PF6 | 1092775-62-6 | | 0.25g | eMolecules | ₹ 20,655.04 | |
 | 1092775-62-6 | [Ir{dFCF3ppy}2(bpy)]PF6 | A2B Chem | ₹ 2,652.36 - ₹ 19,336.56 |
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Description
- Application: When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
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form: powder
Quality Level: 100
reaction suitability: core: iridiumreagent type: catalystreaction type: Photocatalysis
photocatalyst activation: 450 nm
SMILES string: FP(F)(F)(F)F.FC1=CC(F)=C(C2=[N]3C=C(C(F)(F)F)C=C2)C([Ir+]345([N]6=C(C7=CC=CC=[N]75)C=CC=C6)[N]8=C(C9=C(F)C=C(F)C=C94)C=CC(C(F)(F)F)=C8)=C1.[F-]
InChI: 1S/2C12H5F5N.C10H8N2.F5P.FH.Ir/c2*13-8-2-3-9(10(14)5-8)11-4-1-7(6-18-11)12(15,16)17;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-6(2,3,4)5;;/h2*1-2,4-6H;1-8H;;1H;/q;;;;;+1/p-1
InChI key: DZIQZTFRUCLPRL-UHFFFAOYSA-M
form:
powder
Quality Level:
100
reaction suitability:
core: iridiumreagent type: catalystreaction type: Photocatalysis
photocatalyst activation:
450 nm
SMILES string:
FP(F)(F)(F)F.FC1=CC(F)=C(C2=[N]3C=C(C(F)(F)F)C=C2)C([Ir+]345([N]6=C(C7=CC=CC=[N]75)C=CC=C6)[N]8=C(C9=C(F)C=C(F)C=C94)C=CC(C(F)(F)F)=C8)=C1.[F-]
InChI:
1S/2C12H5F5N.C10H8N2.F5P.FH.Ir/c2*13-8-2-3-9(10(14)5-8)11-4-1-7(6-18-11)12(15,16)17;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-6(2,3,4)5;;/h2*1-2,4-6H;1-8H;;1H;/q;;;;;+1/p-1
InChI key:
DZIQZTFRUCLPRL-UHFFFAOYSA-M
form: powder
Quality Level: 100
reaction suitability: core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystreaction type: Cross Couplings
photocatalyst activation: __
SMILES string: CNC1=C(C2=C([Pd]OS(=O)(C)=O)C=CC=C2)C=CC=C1.COC3=CC=CC(OC)=C3C4=CC=CC=C4P(C5CCCCC5)C6CCCCC6
InChI: 1S/C26H35O2P.C13H12N.CH4O3S.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h9-11,16-21H,3-8,12-15H2,1-2H3;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key: ISSWOKPFLWDXSU-UHFFFAOYSA-M
form:
powder
Quality Level:
100
reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystreaction type: Cross Couplings
photocatalyst activation:
__
SMILES string:
CNC1=C(C2=C([Pd]OS(=O)(C)=O)C=CC=C2)C=CC=C1.COC3=CC=CC(OC)=C3C4=CC=CC=C4P(C5CCCCC5)C6CCCCC6
InChI:
1S/C26H35O2P.C13H12N.CH4O3S.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h9-11,16-21H,3-8,12-15H2,1-2H3;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key:
ISSWOKPFLWDXSU-UHFFFAOYSA-M
form: powder
Quality Level: 100
reaction suitability: __
photocatalyst activation: __
SMILES string: Cl.NCC(F)F
InChI: 1S/C2H5F2N.ClH/c3-2(4)1-5;/h2H,1,5H2;1H
InChI key: YSVKPVHTHFECBE-UHFFFAOYSA-N
form:
powder
Quality Level:
100
reaction suitability:
__
photocatalyst activation:
__
SMILES string:
Cl.NCC(F)F
InChI:
1S/C2H5F2N.ClH/c3-2(4)1-5;/h2H,1,5H2;1H
InChI key:
YSVKPVHTHFECBE-UHFFFAOYSA-N
form: powder
Quality Level: 100
reaction suitability: core: nickelreagent type: catalyst
photocatalyst activation: __
SMILES string: O=C(N([C@H](C(C=CC=C1)=C1C2)[C@H]2C3)S3(=O)=O)/C=C/C(N4[C@H](C(C=CC=C5)=C5C6)[C@H]6CS4(=O)=O)=O
InChI: 1S/C24H22N2O6S2/c27-21(25-23-17(13-33(25,29)30)11-15-5-1-3-7-19(15)23)9-10-22(28)26-24-18(14-34(26,31)32)12-16-6-2-4-8-20(16)24/h1-10,17-18,23-24H,11-14H2/b10-9+/t17-,18-,23+,24+/m1/s1
InChI key: CZVFUQRTDAQUQL-SKLQJEMHSA-N
form:
powder
Quality Level:
100
reaction suitability:
core: nickelreagent type: catalyst
photocatalyst activation:
__
SMILES string:
O=C(N([C@H](C(C=CC=C1)=C1C2)[C@H]2C3)S3(=O)=O)/C=C/C(N4[C@H](C(C=CC=C5)=C5C6)[C@H]6CS4(=O)=O)=O
InChI:
1S/C24H22N2O6S2/c27-21(25-23-17(13-33(25,29)30)11-15-5-1-3-7-19(15)23)9-10-22(28)26-24-18(14-34(26,31)32)12-16-6-2-4-8-20(16)24/h1-10,17-18,23-24H,11-14H2/b10-9+/t17-,18-,23+,24+/m1/s1
InChI key:
CZVFUQRTDAQUQL-SKLQJEMHSA-N