804975

DTBPF-Pd-G3

Manufacturer: Sigma Aldrich

Synonym(S): 1,1′-Bis(di-tert-butylphosphino)ferrocene Pd G3

Select a Size

Pack Size SKU Availability Price
250 MG 804975-250-MG In Stock ₹ 13,852.80
1 G 804975-1-G In Stock ₹ 43,833.90

804975 - 250 MG

₹ 13,852.80

In Stock

Quantity

1

Base Price: ₹ 13,852.80

GST (18%): ₹ 2,493.504

Total Price: ₹ 16,346.304

form

solid

Quality Level

100

feature

generation 3

reaction suitability

core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

impurities

may contain 10-20% Di-μ-mesylbis[2′-(amino-N)[1,1′-biphenyl]-2-yl-C]dipalladium(II) (Aldrich Number 762156)may contain 5-10% DTBPF (Aldrich Number 695149)may contain 5-10% pentane

mp

87-150 °C (decomposition)

functional group

phosphine

InChI

1S/2C13H22P.C12H10N.CH4O3S.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h2*7-10H,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q;;;;;+1/p-1

InChI key

AGXLTHQKOWPGBX-UHFFFAOYSA-M

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Description

  • General description: DTBPF-Pd-G-3 is a versatile palladium precatalyst developed by Buchwald group. It is widely employed in various cross-coupling reactions involving the formation of C-C, C-N, C-O, C-F, C-CF3, and C-S bonds. Precatalysts effectively generate active catalytic species for use in various reactions.
  • Application: Pd precatalyst for cross-coupling. Buchwald Third Generation Palladium Precatalyst.

SAFETY INFORMATION

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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form:
solid

Quality Level:
100

feature:
generation 3

reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

impurities:
may contain 10-20% Di-μ-mesylbis[2′-(amino-N)[1,1′-biphenyl]-2-yl-C]dipalladium(II) (Aldrich Number 762156)may contain 5-10% DTBPF (Aldrich Number 695149)may contain 5-10% pentane

mp:
87-150 °C (decomposition)

functional group:
phosphine

InChI:
1S/2C13H22P.C12H10N.CH4O3S.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h2*7-10H,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q;;;;;+1/p-1

InChI key:
AGXLTHQKOWPGBX-UHFFFAOYSA-M

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InChI:
1S/2C17H14P.C12H10N.CH4O3S.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h2*1-14H;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q;;;;;+1/p-1

InChI key:
ASVGFZMDZZREFR-UHFFFAOYSA-M

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