(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
≥97%
Manufacturer: Sigma Aldrich
CAS Number: 158923-11-6
Synonym(S): (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)ferrocene (acc to CAS), Josiphos SL-J009-1
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 88733-100-MG | In Stock | ₹ 14,191.58 |
| 500 MG | 88733-500-MG | In Stock | ₹ 43,960.33 |
| 1 G | 88733-1-G | In Stock | ₹ 65,653.63 |
| 5 G | 88733-5-G | In Stock | ₹ 2,09,214.78 |
88733 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 14,191.58
GST (18%): ₹ 2,554.484
Total Price: ₹ 16,746.064
Quality Level
100
Assay
≥97%
form
powder
optical purity
ee: ≥99%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligandreaction type: Cross Couplings
functional group
phosphine
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(C3CCCCC3)C4CCCCC4)P(C(C)(C)C)C(C)(C)C
InChI
1S/C27H47P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h14,19-23H,8-13,15-18H2,1-7H3;1-5H;/t21-;;/m1../s1
InChI key
FFFWTQLOUUWUJJ-GHVWMZMZSA-N
Other Options
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Description
- General description: (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (CyPF-tBu) is a chiral ferrocenyl diphosphine ligand.[1]
- Application: It may be used as a ligand in the palladium catalyzed hetero cross-coupling between aryl bromides/aryl triflates with potassium thioacetate to form S-aryl thioacetates.[2]
- Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Quality Level: 100
Assay: ≥97%
form: powder
optical purity: ee: ≥99%
reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligandreaction type: Cross Couplings
functional group: phosphine
SMILES string: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(C3CCCCC3)C4CCCCC4)P(C(C)(C)C)C(C)(C)C
InChI: 1S/C27H47P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h14,19-23H,8-13,15-18H2,1-7H3;1-5H;/t21-;;/m1../s1
InChI key: FFFWTQLOUUWUJJ-GHVWMZMZSA-N
Quality Level: 100
Assay: ≥97%
form: powder
optical purity: ee: ≥99%
reaction suitability: __
functional group: __
SMILES string: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(C3CCCCC3)C4CCCCC4)P(C(C)(C)C)C(C)(C)C
InChI: 1S/C27H47P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h14,19-23H,8-13,15-18H2,1-7H3;1-5H;/t21-;;/m0../s1
InChI key: FFFWTQLOUUWUJJ-FGJQBABTSA-N
Quality Level: __
Assay: __
form: __
optical purity: __
reaction suitability: __
functional group: __
SMILES string: __
InChI: __
InChI key: __